| Identification | Back Directory | [Name]
MEPANIPYRIM | [CAS]
110235-47-7 | [Synonyms]
FRUPICA
MEPANIPYRIM
Mepanioyrim
mepanipyrin
Mepanipyrim-D5
Mepanipyrim 50
Mepanipyrim [iso]
MEPANIPYRIM STANDARD
Mepanipyrim@100 μg/mL in AcCN
mepanipyrim (bsi, draft e-iso)
MepanipyrimSolution,100mg/L,1ml
MepanipyrimSolution,1,000mg/L,1ml
Mepanipyrim@1000 μg/mL in Acetonitrile
N-(4-methyl-6prop-1-ynylpyrimidin-2-yl)anikine
N-(4-Methyl-6-prop-1-ynylpyrimidin-2-yl)-aniline
4-methyl-n-phenyl-6-(1-propynyl)-2-pyrimidinamin
4-METHYL-N-PHENYL-6-(1-PROPYNYL)-2-PYRIMIDINAMINE
4-methyl-N-phenyl-6-(prop-1-ynyl)pyrimidin-2-amine
2-Pyrimidinamine, 4-methyl-N-phenyl-6-(1-propynyl)-
4-Methyl-N-phenyl-6-(prop-1-yn-1-yl)pyriMidin-2-aMine
2-Pyrimidinamine, 4-methyl-N-phenyl-6-(1-propyn-1-yl)-
N-(4-Methyl-6-prop-1-ynylpyrimidin-2-yl)aniline (iupac) | [EINECS(EC#)]
432-140-7 | [Molecular Formula]
C14H13N3 | [MDL Number]
MFCD01656050 | [MOL File]
110235-47-7.mol | [Molecular Weight]
223.27 |
| Chemical Properties | Back Directory | [Melting point ]
125-126° (Maeno); also reported as 132.8° (Hayashi) | [Boiling point ]
418.2±47.0 °C(Predicted) | [density ]
1.16±0.1 g/cm3(Predicted) | [vapor pressure ]
2.32 x l0-5 Pa (20 °C) | [Fp ]
131 °C | [storage temp. ]
0-6°C | [solubility ]
Chloroform (Slightly), Methanol (Slightly) | [form ]
neat | [pka]
4.5 (est. base) | [Water Solubility ]
3.1 mg l-1(20 °C) | [color ]
White to Off-White | [LogP]
3.280 | [EPA Substance Registry System]
Mepanipyrim (110235-47-7) |
| Safety Data | Back Directory | [Hazard Codes ]
N,Xn | [Risk Statements ]
51/53-50/53-40 | [Safety Statements ]
60-61-46-36/37 | [RIDADR ]
UN3077 9/PG 3 | [WGK Germany ]
2 | [RTECS ]
UV6261540 | [Toxicity]
LD50 in mice, rats, bobwhite, mallard (mg/kg): >5000, >5000, >2250, >2250 orally; in rats (mg/kg): >2000 dermally; LC50 in bluegill, rainbow trout (mg/l): 3.8, 3.1 (Maeno) |
| Hazard Information | Back Directory | [Uses]
Agricultural fungicide. | [Uses]
Mepanipyrim is a non-systemic fungicide that provides preventative
control of diseases in pome fruits (scab), vines, strawberries, tomatoes
and cucumbers (grey mould) and peaches (brown rots) caused by Botrytis
cinerea, Venturia inaequaris and Monilinia fructicola. | [Uses]
Mepanipyrim is an anilinopyrimidine fungicide which have been used in the management of fungal diseases in strawberries. | [Definition]
ChEBI: A member of the class of aminopyrimidines that is N-phenylpyrimidin-2-amine carrying additional methyl and 1-propynyl substituents at positions 4 and 6 respectively. A fungicide used to control a wide range of diseases including grey mou
d on strawberries, tomatoes and cucumabers, and scab on apples and pears. | [Metabolic pathway]
By tomato seedlings, 14C-mepanipyrim is
biotransformed via the pathways including elimination
of the phenyl group, hydroxylation of the propynyl
moiety, and hydroxylation at the phenyl ring to yield
several kinds of metabolite, and 2- and 4-[4-methyl-6-
(1-propynyl)pyrimidin-2-ylamino]phenols, 1-(2-anilino-6-
methylpyrimidin-4-yl)-2-propanol, and 4-methyl-6-(1-
propynyl)pyrimidin-2-ylamine are tentatively identified
as major metabolites. In soils under laboratory
conditions, 14C-mepanipyrim undergoes degradation to
give the degradation products and the main pathway
is elimination of the phenyl group. | [Degradation]
Mepanipyrim (1) is stable to hydrolytic degradation in the pH range
4-9 with a DT50 >1 year. It decomposed rapidly in water when exposed
to light (DT50 13 days) (PM). |
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