ChemicalBook--->CAS DataBase List--->122-56-5

122-56-5

122-56-5 Structure

122-56-5 Structure
IdentificationBack Directory
[Name]

TRIBUTYLBORANE
[CAS]

122-56-5
[Synonyms]

Tributylboron
Boronbutoxide
TRIBUTYLBORANE
tributyl-boran
Tributylborine
Borane,tributyl-
TRI-N-BUTYLBORON
Borane, tributyl-
Tri-n-butylborane
tri-n-butylborane,
Tributylborane,98%
tri-n-butylborane,tnbb
Tributylborane solution
1.0Msolutionintetrahydrofuran
Tributylborane, 1M solution in THF
Tri-n-butylborane, 1M soln. in THF
Tributylborane solution 1.0 M in THF
Tributylborane1M solution in THFAcroSeal§3
Tributylborane, 1M solution in THF, AcroSeal
Tributylborane, 1M Solution in Tetrahydrofuran
Tributylborane, 1.0 M solution in THF, SpcSeal
TRIBUTYLBORANE, 1.0M SOLUTION IN DIETHYL ETHER
TRIBUTYLBORANE, 1.0M SOLUTION IN TETRAHY DROFURAN
[EINECS(EC#)]

204-554-6
[Molecular Formula]

C12H27B
[MDL Number]

MFCD00009423
[MOL File]

122-56-5.mol
[Molecular Weight]

182.15
Chemical PropertiesBack Directory
[Appearance]

Colorless pyrophoric fluid. Insoluble in water; soluble in most organic solvents.
[Melting point ]

-34 °C
[Boiling point ]

109 °C20 mm Hg(lit.)
[density ]

0.834 g/mL at 25 °C
[refractive index ]

1.4285
[Fp ]

1 °F
[storage temp. ]

Flammables area
[solubility ]

Benzene, Tetrahydrofuran
[form ]

Solution
[color ]

Clear colorless to light yellow
[Water Solubility ]

Not miscible or difficult to mix with water.
[Sensitive ]

Air Sensitive
[Exposure limits]

ACGIH: TWA 50 ppm; STEL 100 ppm (Skin)
OSHA: TWA 200 ppm(590 mg/m3)
NIOSH: IDLH 2000 ppm; TWA 200 ppm(590 mg/m3); STEL 250 ppm(735 mg/m3)
[InChIKey]

CMHHITPYCHHOGT-UHFFFAOYSA-N
[Uses]

Petrochemical industry, organic reactions, catalyst.
[CAS DataBase Reference]

122-56-5
[EPA Substance Registry System]

Borane, tributyl- (122-56-5)
Hazard InformationBack Directory
[Chemical Properties]

colorless to pale yellow liquid
[Synthesis Reference(s)]

The Journal of Organic Chemistry, 51, p. 427, 1986 DOI: 10.1021/jo00354a002
Tetrahedron Letters, 26, p. 4311, 1985 DOI: 10.1016/S0040-4039(00)98721-5
[Hazard]

Flammable, dangerous fire risk, store and use in inert atmosphere, ignites spontaneously in air.
Safety DataBack Directory
[Hazard Codes ]

F,Xn,C
[Risk Statements ]

17-34-40-36/37/38-20/21/22-11-22-19-37
[Safety Statements ]

7-23-26-36/37/39-43-45-16
[RIDADR ]

UN 2845 4.2/PG 1
[WGK Germany ]

1
[RTECS ]

ED1850000
[TSCA ]

Yes
[HazardClass ]

4.2
[PackingGroup ]

I
[HS Code ]

29310099
[Safety Profile]

Poison by intravenous route. Moderately toxic by ingestion. A very dangerous fire hazard when exposed to heat or flame; can ignite spontaneously. When heated to decomposition it emits acrid smoke and irritating fumes. See also BORANES.
Raw materials And Preparation ProductsBack Directory
[Preparation Products]

DIBUTYLBORON TRIFLUOROMETHANESULFONATE-->1-Naphthalenemethanol-->2-METHYL-3-HEPTANONE-->2,5-Dimethylthiophene-3-boronic acid-->4-Butylbenzoic acid
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