ChemicalBook--->CAS DataBase List--->7757-88-2

7757-88-2

7757-88-2 Structure

7757-88-2 Structure
IdentificationBack Directory
[Name]

MAGNESIUM SULFITE
[CAS]

7757-88-2
[Synonyms]

Einecs 231-825-6
MAGNESIUM SULFITE
magnesium sulphite
Sulfurous acid magnesium salt
sulfurousacid,magnesiumsalt(1:1)
[EINECS(EC#)]

231-825-6
[Molecular Formula]

MgO3S
[MDL Number]

MFCD00040664
[MOL File]

7757-88-2.mol
[Molecular Weight]

104.37
Chemical PropertiesBack Directory
[Appearance]

White, crystalline powder. Slightly soluble in water; insoluble in alcohol.
[density ]

1.725 g/cm3
[Water Solubility ]

g/100g solution H2O: 0.338 (0°C), 0.646 (25°C), 0.615 (98°C); solid phase, MgSO3 · 6H2O (0°C, 25°C), MgSO3 ·3H2O (98°C) [KRU93]
[Solubility Product Constant (Ksp)]

pKsp: 2.50
[Uses]

Manufacture of paper pulp (as bisulfite).
[EPA Substance Registry System]

Sulfurous acid, magnesium salt (1:1) (7757-88-2)
Hazard InformationBack Directory
[Chemical Properties]

White, crystalline powder. Slightly soluble in water; insoluble in alcohol.
[Preparation]

Magnesium Sulfite can be prepared by the reaction of a magnesium hydroxide slurry and SO2 gas:
Mg(OH)2+ SO2(gas) +H2O→MgSO3·6H2O
If the solution temperature is kept below 40°C, the hexahydrate results. Above 40°C, the trihydrate, MgSO3·3H2O, is the usual product. Magnesium sulfite may also be prepared by adding a solution of sodium sulfite to a solution of magnesium chloride. The mix is kept at 25°C for 1–2 h and the solid phase which forms is separated and washed with isopropanol and dried at 60°C. Again, the hexahydrate results.
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