Peri acid
- CAS No.
- 82-75-7
- Chemical Name:
- Peri acid
- Synonyms
- 8-AMINONAPHTHALENE-1-SULFONIC ACID;PERI ACID;1,8-AMINO ACID;Perigastric acid;Schollkopf's acid (VAN);8-SULFO-1-NAPHTHYLAMINE;1.8 Clevs Acid(Peri Acid);1-AMINO-8-SULFONAPHTHALENE;8-Naphthol-1-sulfonic acid;Peri acid ISO 9001：2015 REACH
- CBNumber:
- CB0680336
- Molecular Formula:
- C10H9NO3S
- Molecular Weight:
- 223.25
- MDL Number:
- MFCD00035730
- MOL File:
- 82-75-7.mol
| Melting point | >350°C |
|---|---|
| Boiling point | 220°C (rough estimate) |
| Density | 1.3588 (rough estimate) |
| refractive index | 1.6500 (estimate) |
| pka | pK1: 5.03 (25°C) |
| form | powder to crystal |
| color | Light yellow to Brown |
| Water Solubility | 0.2g/L(21 ºC) |
| Merck | 14,6405 |
| BRN | 983230 |
| CAS DataBase Reference | 82-75-7(CAS DataBase Reference) |
| FDA UNII | 0D93Y3MXV4 |
| EPA Substance Registry System | 1-Naphthalenesulfonic acid, 8-amino- (82-75-7) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
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|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H335-H315-H319 | |||||||||
| Precautionary statements | P264-P280-P302+P352+P332+P313+P362+P364-P305+P351+P338+P337+P313-P261-P280a-P304+P340-P305+P351+P338-P405-P501a | |||||||||
| Hazard Codes | C | |||||||||
| Risk Statements | 34 | |||||||||
| Safety Statements | 26-27-36-45 | |||||||||
| TSCA | Yes | |||||||||
| HS Code | 29214500 | |||||||||
| NFPA 704 |
|
Peri acid price More Price(30)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| TCI Chemical | A0350 | 8-Amino-1-naphthalenesulfonic Acid >98.0%(HPLC) | 82-75-7 | 25g | $30 | 2024-03-01 | Buy |
| TCI Chemical | A0350 | 8-Amino-1-naphthalenesulfonic Acid >98.0%(HPLC) | 82-75-7 | 100g | $79 | 2024-03-01 | Buy |
| Alfa Aesar | L17616 | 8-Aminonaphthalene-1-sulfonic acid, 98% | 82-75-7 | 100g | $66.3 | 2021-12-16 | Buy |
| Alfa Aesar | L17616 | 8-Aminonaphthalene-1-sulfonic acid, 98% | 82-75-7 | 25g | $29.7 | 2021-12-16 | Buy |
| TCI Chemical | A0350 | 8-Amino-1-naphthalenesulfonic Acid >98.0%(HPLC) | 82-75-7 | 500g | $119 | 2023-01-07 | Buy |
Peri acid Chemical Properties,Uses,Production
Chemical Properties
Dark green powder. 1-Aminonaphthalene-8-sulfonic acid [82- 75-7]. (8-aminonaphthalene-1-sulfonic acid), Peri acid, C10H9NO3S, Mr 223.24, crystallizes as the monohydrate and is sparingly soluble even in boiling water. The sodium salt is also sparingly soluble in water. Caustic fusion at 200℃ produces 8-amino-1- naphthol, whereas slow hydrolysis with 10 % sodium hydroxide at 220 – 260℃ yields 1,8- dihydroxynaphthalene. Sulfonation with cold 10 % oleum produces 1-aminonaphthalene-4,8- disulfonic acid, whereas hot concentrated sulfuric acid results in slow isomerization into naphthionic acid.
Uses
Intermediate of dyestuff. Dehydration with phosphorus oxychloride yields naphthosultam, and diazotization followed by hydrolysis results in naphthosultone, the intermediate for 1- hydroxynaphthalene-8-sulfonic acid. Diazotization followed by a Sandmeyer cyanide reaction gives 8-cyanonaphthalene-1-sulfonic acid, one of the most industrially important Sandmeyer reaction products because the nitrile forms the lactam, naphthostyril [130-00-7], upon treatment with concentrated alkali at 185℃. Hydrolysis of naphthostyril with dilute alkali yields 8-aminonaphthalene-1-carboxylic acid, which is the key intermediate for production of anthanthrone vat dyes via 1,10 -binaphthyl8,80 -dicarboxylic acid.
Production Methods
Naphthalene is converted to naphthalene-1-sulfonic acid. The crude sulfonation product is diluted with sulfuric acid, and 67.5 % nitric acid is added slowly at 30℃ to give the 5- and 8-nitro derivatives. The products are converted to the readily soluble magnesium salts by addition of a slurry of dolomite. The reaction mixture is neutralized with chalk and filtered hot. The filtrate is run into a suspension of iron powder in boiling water, which is kept slightly acidic with sulfuric acid. When reduction is complete, dissolved iron is precipitated by addition of magnesia, the iron residues are filtered off while hot, and the resulting liquor is acidified to pH 4.5 with sulfuric acid to give 99 % pure Peri acid in 48 % yield. The filtrates are further acidified to precipitate crude Laurent’s acid. This may be purified via its magnesium salt to give a 17 % yield of pure 1,5-isomer.
Peri acid Preparation Products And Raw materials
Raw materials
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Preparation Products
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| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Hebei Mojin Biotechnology Co., Ltd | +8613288715578 | sales@hbmojin.com | China | 12471 | 58 |
| Hebei Yanxi Chemical Co., Ltd. | +8617531190177 | peter@yan-xi.com | China | 6000 | 58 |
| Shenzhen Nexconn Pharmatechs Ltd | +86-755-89396905 +86-15013857715 | admin@nexconn.com | China | 10248 | 58 |
| Hubei Jusheng Technology Co.,Ltd. | 18871490254 | linda@hubeijusheng.com | CHINA | 28180 | 58 |
| Hebei Guanlang Biotechnology Co., Ltd. | +86-19930503282 | alice@crovellbio.com | China | 8822 | 58 |
| Xiamen AmoyChem Co., Ltd | +86-592-6051114 +8618959220845 | sales@amoychem.com | China | 6387 | 58 |
| Hubei xin bonus chemical co. LTD | 86-13657291602 | linda@hubeijusheng.com | CHINA | 22968 | 58 |
| CONIER CHEM AND PHARMA LIMITED | +8618523575427 | sales@conier.com | China | 49391 | 58 |
| career henan chemical co | +86-0371-86658258 15093356674; | factory@coreychem.com | China | 29826 | 58 |
| Shaanxi Dideu Medichem Co. Ltd | +86-029-81148696 +8615536356810 | 1047@dideu.com | China | 2745 | 58 |
View Lastest Price from Peri acid manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
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2023-10-26 | Peri acid
82-75-7
|
US $30.00-12.00 / kg | 1kg | 0.99 | 20 tons | Hebei Yanxi Chemical Co., Ltd. | |
 |
2023-09-06 | Peri acid
82-75-7
|
US $0.00-0.00 / KG | 1KG | 99% | 500000kg | Hebei Guanlang Biotechnology Co., Ltd. | |
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2023-08-26 | Peri acid
82-75-7
|
US $0.00 / KG | 1KG | 99% | 50000KG/month | Hebei Mojin Biotechnology Co., Ltd |