ChemicalBook >> CAS DataBase List >>2-Aminodiphenylamine

2-Aminodiphenylamine

CAS No.
534-85-0
Chemical Name:
2-Aminodiphenylamine
Synonyms
C.I. 50005;o-Semidine;TIMTEC-BB SBB000244;O-AMINODIPHENYLAMINE;2-AMINODIPHENYLAMINE;LABOTEST-BB LT00080731;N-Phenyl-2-aminoaniline;ORTHO-AMINODIPHENYLAMINE;N-(2-aminophenyl)aniline;2-Aminodiphenylamine >
CBNumber:
CB4767341
Molecular Formula:
C12H12N2
Molecular Weight:
184.24
MDL Number:
MFCD00007685
MOL File:
534-85-0.mol
MSDS File:
SDS
Last updated:2024-04-16 16:23:18

2-Aminodiphenylamine Properties

Melting point 77-80 °C(lit.)
Boiling point 108 °C / 0.4mmHg
Density 1.1160 (rough estimate)
refractive index 1.6266 (estimate)
storage temp. Keep in dark place,Inert atmosphere,Room temperature
pka 4.45±0.10(Predicted)
form Crystalline Powder
color Pink-violet or gray-brown
Water Solubility Soluble in acetone, chloroform and benzene. Insoluble in water.
BRN 908984
InChIKey NFCPRRWCTNLGSN-UHFFFAOYSA-N
CAS DataBase Reference 534-85-0(CAS DataBase Reference)
FDA UNII G2X60K1Y26
NIST Chemistry Reference 1,2-Benzenediamine, n-phenyl-(534-85-0)
EPA Substance Registry System 1,2-Benzenediamine, N-phenyl- (534-85-0)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H302+H332-H315
Precautionary statements  P261-P264-P270-P301+P312-P302+P352-P304+P340+P312
Hazard Codes  Xn,Xi
Risk Statements  20/22-38-36/37/38
Safety Statements  22-24-28A-26
RIDADR  2811
WGK Germany  3
8
Hazard Note  Irritant
TSCA  Yes
HazardClass  6.1(b)
PackingGroup  III
HS Code  29215990
NFPA 704
0
2 0

2-Aminodiphenylamine price More Price(22)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich P28352 N-Phenyl-o-phenylenediamine 98% 534-85-0 10g $113 2024-03-01 Buy
TCI Chemical A2129 2-Aminodiphenylamine >98.0%(GC)(T) 534-85-0 5g $29 2024-03-01 Buy
TCI Chemical A2129 2-Aminodiphenylamine >98.0%(GC)(T) 534-85-0 25g $114 2024-03-01 Buy
Alfa Aesar L11616 N-Phenyl-o-phenylenediamine, 98% 534-85-0 5g $30.65 2024-03-01 Buy
Alfa Aesar L11616 N-Phenyl-o-phenylenediamine, 98% 534-85-0 25g $97.65 2024-03-01 Buy
Product number Packaging Price Buy
P28352 10g $113 Buy
A2129 5g $29 Buy
A2129 25g $114 Buy
L11616 5g $30.65 Buy
L11616 25g $97.65 Buy

2-Aminodiphenylamine Chemical Properties,Uses,Production

Chemical Properties

White to Light yellow to Light red powder to crystal

Uses

N-Phenyl-o-phenylenediamine is also used as an intermediate in organic synthesis and pharmaceuticals.

Synthesis

The synthesis of 2-Aminodiphenylamine is as folliows:
Reaction flask was added 0.108 g of o-phenylenediamine (1 mmol), phenylhydrazine0.216 g (2 mmol), CuPc 0.058 Ke (0.1 mmol), Cu (OAc) 2 0.02 g (0.1 mmol) and 10 ml ofacetonitrile, 15 °C reaction; TLC until the reaction was followed completely finished;the crude product after the reaction was subjected to column chromatography (petroleumether: ethyl acetate = 100: 1) to give the desired product (71% yield).
synthesis of 2-Aminodiphenylamine.png

storage

Keep container tightly closed. Store in cool, dry conditions in well sealed containers. It is sensitive to light. Store at room temperature. Incompatible with acid chlorides, acid anhydrides, chloroformates and strong oxidizing agents.

Purification Methods

Crystallise the amine from H2O. [Beilstein 13 IV 43.]

95-54-5
100-63-0
534-85-0
Synthesis of 2-Aminodiphenylamine from o-Phenylenediamine and Phenylhydrazine
Global( 271)Suppliers
Supplier Tel Email Country ProdList Advantage
Chemsigma International Co., Ltd.
+86-18136843612 +86-19951791336 info@chemsigma.com China 1095 58
Nanjing Kaitian Chemical Co., LTD
+undefined13337835376 kt_chem@126.com China 40 58
Nanjing Triumpharm Co.,Ltd
+86-02586182925 +86-15105172550 info@triumpharm.com China 129 58
Hebei Guanlang Biotechnology Co,.LTD
+8619930503252 daisy@crovellbio.com China 5963 58
Anhui Yiao New Material Technology Co., Ltd
+86-199-55145978 +8619955145978 sales8@anhuiyiao.com China 253 58
Henan Fengda Chemical Co., Ltd
+86-371-86557731 +86-13613820652 info@fdachem.com China 18232 58
Capot Chemical Co.,Ltd.
571-85586718 +8613336195806 sales@capotchem.com China 29797 60
Shanghai Daken Advanced Materials Co.,Ltd
+86-371-66670886 info@dakenam.com China 15957 58
Henan Tianfu Chemical Co.,Ltd.
+86-0371-55170693 +86-19937530512 info@tianfuchem.com China 21689 55
career henan chemical co
+86-0371-86658258 sales@coreychem.com China 29914 58

View Lastest Price from 2-Aminodiphenylamine manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
N-Phenyl-o-phenylenediamine pictures 2024-05-15 N-Phenyl-o-phenylenediamine
534-85-0
US $0.00 / KG 1KG 99% 1 ton Anhui Yiao New Material Technology Co., Ltd
N-Phenyl-o-phenylenediamine pictures 2024-05-15 N-Phenyl-o-phenylenediamine
534-85-0
US $0.00 / KG 1KG 99% 1 ton Anhui Yiao New Material Technology Co., Ltd
	2-Aminodiphenylamine pictures 2024-04-16 2-Aminodiphenylamine
534-85-0
US $5.00-0.10 / KG 1KG 99% g-kg-tons, free sample is available Henan Fengda Chemical Co., Ltd
N1-phenylbenzene-1,2-diamine N-phenyl-1,2-diamino-benzene 2-AMINODIPHENYLAMINE 97+% ORTHO-AMINODIPHENYLAMINE ORTHO-PHENYLENEDIAMINE,N-PHENYL- 2-Aminodiphenylamine, GC 98+% N-Phenyl-1,2-benzenediamine N-Phenyl-2-aminoaniline N-Phenyl-o-phenylenediamine,97% 1,2-BenzenediaMine, N1-phenyl- N-Phenyl-o-phenylenediaMine 98% TIMTEC-BB SBB000244 N-(2-AMINOPHENYL)-N-PHENYLAMINE N-PHENYL-1,2-PHENYLENEDIAMINE N-PHENYL-O-PHENYLENEDIAMINE O-AMINODIPHENYLAMINE LABOTEST-BB LT00080731 2-AMINODIPHENYLAMINE C.I. 50005 N-Phenyl-o-phenylenediamine 2-Aminodiphenylamine for synthesis o-Phenylenediamine, N-phenyl- o-Semidine N-(2-aminophenyl)aniline n-phenyl-2-benzenediamine 2-Aminodiphenylamine > 2-Aminodiphenylamine ISO 9001:2015 REACH 2-N-phenylbenzene-1,2-diamine 1,2-BENZENEDIAMINE, N-PHENYL- 534-85-0 535-85-0 H2NC6H4NHC6H5 AMINE Polyamines Nitrogen Compounds Organic Building Blocks Building Blocks Nitrogen Compounds Building Blocks Chemical Synthesis Organic Building Blocks Polyamines API intermediates Anilines, Aromatic Amines and Nitro Compounds