メチルヒドラジン

メチルヒドラジン MSDS

1-Methylhydrazine

メチルヒドラジン 化学特性,用途語,生産方法

外観

無色〜わずかにうすい黄色, 澄明の液体

溶解性

水に混和。エタノール, エーテルに可溶。水及びエタノールに溶ける。

解説

monomethylhydrazine．CH6N2(46.07)．CH3NHNH2．メチルアミンとヒドロキシルアミン硫酸エステルから合成する．メチルアミン臭をもつ無色の液体．融点－52.4 ℃，沸点87.5 ℃，引火点 ＜ 26.7 ℃．d²⁵"0.874．水，低級アルコールに易溶，炭化水素に可溶．わずかにアルカリ性を示す．空気中で水を吸収して白煙を生じる．強力な還元剤で，発煙硝酸などの強い酸化剤や炎に触れると発火する．爆発限界は空気中で約2％．ロケット用燃料，化学合成原料として用いられる．LD50 32.5 mg/kg(ラット，経口)．[CAS 60-34-4]
森北出版「化学辞典（第2版）

用途

農薬?医薬原料、ミサイル推進薬

使用上の注意

不活性ガス封入。空気中で、徐々に黄褐色になる。

説明

Methyl hydrazine, CH3NHNH2, is a colorless, hygroscopic liquid with an ammonia-like odor. It is soluble in water, with a specific gravity of 0.87, which is lighter than water. Methyl hydrazine is toxic by inhalation and ingestion, and is a suspected human carcinogen. The TLV ceiling is 0.2 ppm in air, and the IDLH is 50 ppm. The target organs are the central nervous system, respiratory system, liver, blood, eyes, and cardiovascular system. The four-digit UN identification number is 1244. The NFPA 704 designation is health 4, flammability 3, and reactivity 2. The primary uses are as a missile propellant and a solvent.

化学的特性

colourless liquid with an ammonia-like odour

物理的性質

Fuming, clear, colorless liquid with an ammonia-like odor. Odor threshold concentrations ranged from 1 to 3 ppm (quoted, Keith and Walters, 1992).

使用

Methylhydrazine is used in missile propellants and as a solvent and chemical intermediate.

調製方法

Methylhydrazine ignites spontaneously on contact with strong oxidizing agents. It is prepared commercially from the reaction of monochloroamine and monomethylamine.

空気と水の反応

Highly flammable. Often ignites spontaneously. Exposure to air on a large surface may result in spontaneous ignition [Def. Res. and Eng. 27. 1963]. Water soluble. Solutions are highly alkaline and generate heat when water is added.

反応プロフィール

Methylhydrazine is a powerful reducing agent. Ignites upon contact with oxidizing agents i.e. dinitrogen tetraoxide, hydrogen peroxide [Hawley]. Water used to extinguish a fire may cause pollution and should be diked for later disposal. Gives basic solutions with water that generate heat when water is added.

危険性

Flammable, dangerous fire risk, vapors mayexplode, may self-ignite in air and on contact withoxidizing agents. Toxic by ingestion and inhalation.Eye and upper respiratory tract irritant, lung cancerand liver damage. Possible carcinogen.

健康ハザード

Methyl hydrazine vapors are extremely toxic and the liquid is corrosive to skin. Methyl hydrazine is the strongest convulsant and the most toxic of methyl-substituted hydrazine derivatives. It is more toxic than hydrazine. At high doses, it is a strong central nervous system poison that can lead to convulsions and death. Skin rash may be aggravated by skin exposure.

火災危険

Extremely flammable; ignites spontaneously under almost all normal temperature conditions. Water used to extinguish a fire may cause pollution and should be diked for later disposal. Water may be ineffective in extinguishing fires due to the chemical's low flash point. Because of the wide flammability limits, low flash point, and reignition hazard, dry chemicals, carbon dioxide, water spray, and foam may not be as effective as water dilution of fire area. The vapor is heavier than air; thus Methylhydrazine may accumulate sufficiently to flash back. Methylhydrazine fires produce irritating nitrogen oxides. Ignites spontaneously in air when in contact with porous materials (e.g., earth, asbestos, wood, or cloth). Also ignites spontaneously on contact with strong oxidizing agents (e.g., fluorine, chlorine trifluoride, fuming nitric acid, and nitrogen tetroxide). Heat or flame should be avoided because chemical is extremely flammable and explosive.

安全性プロファイル

Suspected carcinogen with experimental carcinogenic, neoplastigenic, tumorigenic, and teratogenic data. Poison by inhalation, ingestion, skin contact, intraperitoneal, subcutaneous, and intravenous routes. Experimental reproductive effects. Human mutation data reported. Corrosive to skin, eyes and mucous membranes. May self-ignite in air. Very dangerous fire hazard when exposed to heat or flame. To fight fire, use alcohol foam, CO2, dry chemical. Explosive in the form of vapor when exposed to heat or flame. A powerful reducing agent. It is hypergolic with many oxidants (e.g., dinitrogen tetraoxide and hydrogen peroxide). When heated to decomposition it emits toxic fumes of NOx.

職業ばく露

MMH has been used as the propellant in liquid propellant rockets; it is also used as a solvent and as an organic intermediate.

発がん性

The carcinogenicity of methylhydrazine has been extensively investigated. In two studies, no compound-related increase in tumor incidence was observed in mice treated orally with methylhydrazine . In other studies, methylhydrazine produced lung tumors in mice and malignant histiocytoma of the liver and cecal tumors in hamsters when administered in drinking water at concentrations of 0.01%. Potential carcinogenicity from vapor exposure to methylhydrazine was also investigated in rats, dogs, hamsters, and mice. Exposures to methylhydrazine at concentrations of 0.02 ppm (rats and mice only) and 0.2, 2, and 5 ppm (rats and hamsters only)were conducted for 6 h/day, 5 days/week, for a year, followed by observation for 1 year.

環境運命予測

Biological. It was suggested that the rapid disappearance of methylhydrazine in sterile and nonsterile soil (Arrendondo fine sand) under aerobic conditions was due to chemical oxidation. Although the oxidation product was not identified, it biodegraded to carbon dioxide in the nonsterile soil. The oxidation product did not degrade in the sterile soil (Ou and Street, 1988).

輸送方法

UN1244 Methylhydrazine, Hazard class: 6.1; Labels: 6.1-Poison Inhalation Hazard, 3-Flammable liquid, 8-Corrosive material, Inhalation Hazard Zone A

純化方法

Dry with BaO, then distil it in a vacuum. Store it under nitrogen. [Beilstein 4 IV 3322.]

不和合性

May form explosive mixture with air. Methyl hydrazine is a highly reactive reducing agent and a medium strong base. May explode if heated. Violent reaction with strong oxidizers, such as fluorine, chlorine, combustibles, nitric acid; hydrogen peroxide. Incompatible with acids, alcohols, glycols, isocyanates, phenols, cresols; porous materials, such as earth, asbestos, wood and cloth. Oxides of iron or copper, manganese, lead, copper or their alloys can lead to fire and explosions. Attacks cork, some plastics, coatings and rubber.

廃棄物の処理

Consult with environmental regulatory agencies for guidance on acceptable disposal practices. Generators of waste containing this contaminant (≥100 kg/mo) must conform to EPA regulations governing storage, transportation, treatment, and waste disposal. There are 2 alternatives: Dilute with water, neutralize with sulfuric acid, then flush to sewer with large volumes of water or incinerate with added flammable solvent in furnace equipped with afterburner and alkaline scrubber.

メチルヒドラジン 上流と下流の製品情報

原材料

準備製品

60-34-4(メチルヒドラジン)キーワード:

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• 60-34-4
• HydraZine,methyl-
• Hydrazinomethane
• 2-Methylhydrazine
• Methylhydrazine,98%
• Methylhydrazine
• MethylHydrazine40%
• METHYLHYDRAZINE (controlled chemical)
• Methylydrazine
• Monomethyl hydrazine (MMH)
• Metylohydrazyna
• metylohydrazyna(polish)
• Rcra waste number P068
• rcrawastenumberp068
• 1-Methylhydrazine
• Methyl Hydrazin 35%
• Methylhydrazine 80% solution
• CH3NHNH2
• Hydrazomethane
• Methylhydrazine,40% aq
• Methylhydrazine, 40wt.% in H2O
• N-METHYLHYDRAZINE
• MMH
• MONOMETHYL HYDRAZINE
• JJJ
• methyl-hydrazin
• METHYL HYDRAZINE SOLUTION 80-85% IN WATER
• メチルヒドラジン
• 2-メチルヒドラジン
• 1-メチルヒドラジン
• モノメチルヒドラジン
• 生化学
• 糖鎖合成用反応剤