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19-Heptyl-10-hydroxy-1,5,10,14-tetraazacyclononadecan-15-one

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19-Heptyl-10-hydroxy-1,5,10,14-tetraazacyclononadecan-15-one Basic information
Product Name:19-Heptyl-10-hydroxy-1,5,10,14-tetraazacyclononadecan-15-one
Synonyms:19-Heptyl-10-hydroxy-1,5,10,14-tetraazacyclononadecan-15-one;Pithecolobine
CAS:22368-82-7
MF:C22H46N4O2
MW:0
EINECS:
Product Categories:
Mol File:22368-82-7.mol
19-Heptyl-10-hydroxy-1,5,10,14-tetraazacyclononadecan-15-one Structure
19-Heptyl-10-hydroxy-1,5,10,14-tetraazacyclononadecan-15-one Chemical Properties
Melting point 67-69°
Boiling point bp0.007 230°
Safety Information
MSDS Information
19-Heptyl-10-hydroxy-1,5,10,14-tetraazacyclononadecan-15-one Usage And Synthesis
DescriptionThe bark of Pithecolobiurn sarnan Benth. yields this macro cyclic alkaloid, first obtained by Greshoff who gave it the formula C17H360N 3 and [α]27D - 12.12° (EtOH), yielding a dihydrochloride with [α]27D - 19.3° (H20). It has been stated to yield methylamine and piperidine on distillation with Zn dust. A tripicrolonate is known as colourless, or pale yellow, crystals from MeOH-Me2CO, m.p. 134-5"C. The tetraacetate is a colourless oil.
ReferencesGreshoff., Ber., 23,3541 (1890)
van ltallie.,Pharrn. Weekbl., 69,941 (1932)
Wiesneretal., Can. J. Chern., 30,761 (1952)
Wiesner et aI., J. Arner. Chern. Soc., 75,6348 (1953)
Orr, Wiesner., Chern. & Ind., 672 (1959)
Orr, Weisner., Tetrahedron Lett., No. 16, II (1960)
Structure: Wiesner, MacDonald, Bankiewicz., Can. J. Chern., 46, 1881 (1968)
19-Heptyl-10-hydroxy-1,5,10,14-tetraazacyclononadecan-15-one Preparation Products And Raw materials
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