| Identification | Back Directory | [Name]
N-BUTYLMORPHOLINE | [CAS]
1005-67-0 | [Synonyms]
N-BUTYLMORPHOLINE
4-butyl-morpholin
4-BUTYL-MORPHOLINE
4-n-butylmorpholine
Morpholine, 4-butyl-
n-(n-butyl)morpholine
4-Butylmorpholine > | [Molecular Formula]
C8H17NO | [MDL Number]
MFCD00023401 | [MOL File]
1005-67-0.mol | [Molecular Weight]
143.23 |
| Chemical Properties | Back Directory | [Melting point ]
-57.1°C | [Boiling point ]
78°C/22mmHg(lit.) | [density ]
0.9068 | [refractive index ]
1.4430-1.4470 | [storage temp. ]
Sealed in dry,Room Temperature | [form ]
clear liquid | [pka]
7.66±0.10(Predicted) | [color ]
Colorless to Light yellow to Light orange | [EPA Substance Registry System]
Morpholine, 4-butyl- (1005-67-0) |
| Safety Data | Back Directory | [RIDADR ]
1993 | [RTECS ]
QD8773000 | [TSCA ]
TSCA listed | [HazardClass ]
3 | [PackingGroup ]
III | [HS Code ]
2934999090 | [Toxicity]
rabbit,LD50,skin,1800mg/kg (1800mg/kg),SKIN AND APPENDAGES (SKIN): CORROSIVE: AFTER TOPICAL EXPOSURE,Acute Toxicity Data. Journal of the American College of Toxicology, Part B. Vol. 1, Pg. 13, 1990. |
| Hazard Information | Back Directory | [Synthesis]
General method: A mixture of ionic liquids (1-6) (0.1 g), morpholine (0.55 mmol) and 1-chlorobutane (0.5 mmol) was heated and reacted at 90°C for 3 hours under the protection of inert atmosphere. After completion of the reaction, the reaction mixture was diluted with aqueous NaHCO3 and extracted with ether (Et2O). The organic layers were combined and dried with anhydrous magnesium sulfate (MgSO4). Subsequently, the solvent was evaporated under reduced pressure to give the crude product. The crude product was characterized and analyzed by gas chromatography-mass spectrometry (GC-MS) and nuclear magnetic resonance (NMR) spectroscopy. | [References]
[1] Journal of Molecular Liquids, 2015, vol. 204, p. 210 - 215
[2] Synthetic Communications, 2014, vol. 44, # 5, p. 620 - 632 |
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Sigma-Aldrich
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https://www.sigmaaldrich.cn |
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