| Identification | Back Directory | [Name]
Diacetato{(R)-(-)-5,5'-bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole}ruthenium(II) Ru(OAc)2[(R)-dtbm-segphos] | [CAS]
1025477-38-6 | [Synonyms]
Ru(OAc)2[(R)-dtbm-segphos]
Diacetato{(R)-(-)-5,5'-bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole}ruthenium(II) Ru(OAc)2[(R)-dtbm-segphos]
Diacetato{(R)-(-)-5,5'-bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole}ruthenium(II) Ru(OAc)2[(R)-dtbm-segphos(R)] | [Molecular Formula]
C78H106O12P2Ru | [MDL Number]
MFCD17018804 | [MOL File]
1025477-38-6.mol | [Molecular Weight]
1400.73 |
| Chemical Properties | Back Directory | [storage temp. ]
2-8°C, protect from light, stored under nitrogen | [form ]
solid | [color ]
yellow to brownish-red to dark green | [Sensitive ]
air sensitive |
| Questions And Answer | Back Directory | [Reactions]
- Biaryl bisphosphine ligand with narrow dihedral angle. The DM-SEGPHOS ligand, as the ruthenium complex, gives superior enantioselectivity and diastereoselectivity in the asymmetric hydrogenation of α-substituted-β-ketoesters.
- Ruthenium catalyzed enantioselective synthesis of β amino acids by hydrogenation.
- Ruthenium catalyzed asymmetric hydrogenation of 3-quinuclidinone.
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| Hazard Information | Back Directory | [Uses]
Ru(OAc)2[(S)-dtbm-SEGPHOS®] is a ruthenium catalyst for asymmetric hydrogenation of olefins.
Product can be used with our benchtop hydrogen generator, H-Genie Lite (Z744083) |
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| Company Name: |
LaaJoo
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| Tel: |
021-60702684 18516024827 |
| Website: |
www.chemicalbook.com/ShowSupplierProductsList20079/0_EN.htm |
| Company Name: |
Energy Chemical
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| Tel: |
021-58432009 400-005-6266 |
| Website: |
http://www.energy-chemical.com |
| Company Name: |
Merck KGaA
|
| Tel: |
21-20338288 |
| Website: |
www.sigmaaldrich.cn |
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