ChemicalBook--->CAS DataBase List--->10339-55-6

10339-55-6

10339-55-6 Structure

10339-55-6 Structure
IdentificationBack Directory
[Name]

ETHYL LINALOOL
[CAS]

10339-55-6
[Synonyms]

ETHYL LINALOOL
Ethyl Linanlool
METHYL LINALOOL
Rhodinol (Nature)
3,7-dimethylnona-
Ethyllinalool Technical
3,7-dimethylnona-1,6-dien
3,7-dimethyl-6-nonadien-3-ol
3,7-dimethylnona-1,6-dien-3-ol
6-Nonadien-3-ol,3,7-dimethyl-1
3,7-dimethyl-1,6-nonadien-3-ol
1,6-Nonadien-3-ol, 3,7-dimethyl-
6-NONADIEN-3-OL, 3,7-DIMETHYL-1,85%
[EINECS(EC#)]

233-732-6
[Molecular Formula]

C12H22O
[MDL Number]

MFCD00135350
[MOL File]

10339-55-6.mol
[Molecular Weight]

182.3
Chemical PropertiesBack Directory
[Boiling point ]

132℃ (86 Torr)
[density ]

0.857±0.06 g/cm3 (20 ºC 760 Torr)
[vapor pressure ]

18Pa at 25℃
[refractive index ]

1.4603 (589.3 nm 25℃)
[Fp ]

90.9±15.0℃
[pka]

14.45±0.29(Predicted)
[color ]

Colourless slightly oily liquid.
[Odor]

at 100.00 %. fresh bois de rose herbal wet green lavender bergamot
[Odor Type]

floral
[Water Solubility ]

656mg/L at 20℃
[Cosmetics Ingredients Functions]

PERFUMING
FRAGRANCE
[InChI]

InChI=1S/C11H20O/c1-5-10(3)8-7-9-11(4,12)6-2/h6,8,12H,2,5,7,9H2,1,3-4H3
[InChIKey]

KRLBLPBPZSSIGH-UHFFFAOYSA-N
[SMILES]

C=CC(C)(O)CCC=C(C)CC
[LogP]

3.3
[EPA Substance Registry System]

1,6-Nonadien-3-ol, 3,7-dimethyl- (10339-55-6)
Safety DataBack Directory
[Symbol(GHS) ]

Exclamation Mark (GHS07)
GHS07
[Signal word ]

Warning
[Hazard statements ]

H319-H317-H315
[Precautionary statements ]

P261-P272-P280-P302+P352-P333+P313-P321-P363-P501-P264-P280-P305+P351+P338-P337+P313P-P264-P280-P302+P352-P321-P332+P313-P362
[TSCA ]

TSCA listed
[REACH Registrations]

Active
[Toxicity]

Both the acute oral LD50 value in rats and the acute dermal LD50 value in rabbits exceeded 5 g/kg (Moreno, 1975).
Raw materials And Preparation ProductsBack Directory
[Preparation Products]

4-Methyl-2-(2-methyl-1-propenyl)tetrahydropyran (cis- and trans- mixture)
Hazard InformationBack Directory
[Chemical Properties]

Clear colorless to pale yellowish liquid.
[Physical properties]

Colorless slightly oily liquid. Very slightly soluble in Mater, soluble in alcohol and oils.
[Occurrence]

Has apparently not been reported to occur in nature.
[Uses]

Ethyl Linalool is fresh bois de rose herbal wet green lavender bergamot. It has a floral, fresh, bergamot character and is sweeter and less agrestic than Linalool. As with Linalool, it is used in a wide variety of notes for floral bouquets.
[Preparation]

From methyl ethyl ketone and acetylene through a series of reactions (Bedoukian, 1967).
[Metabolism]

Tertiary alcohols are not readily metabolized and may be excreted in the urine both unchanged and highly conjugated with glucuronic acid. In rabbits, carbon-carbon double bonds make little difference to the extent of conjugation of terf-hexyl alcohols (Williams, 1959).
Questions And AnswerBack Directory
[Aroma]

Floral, only slightly woody-green, soft odor of moderate tenacity. The odor type compared to Linalool indicates that "Ethyl Iinalool" is softer, more waxy, less volatile, less woodygrecn and overall more floral. It is more Coriander-like, less Bois-de-Rose-like.
[Uses in Perfume]

Ethyl linalool has been suggested for use in perfume compositions as a modifier for LinaIool with certain advantages over that marerial. Ethyl Iinalool has a somewhat slower rate of evaporation and is easier to work with, needs only normal fixation, and blends with more materials. It introduces softer, more floralwoody, less citrusy notes, according to the composition in which it is used. Along with Ethyl Iinalyl acetate, it forms a pleasant Bergamot-type background note even in soap perfumes, a combination which is more stable than Bergamot oil itself.
The alcohol is also an interesting item in Muguet, Lilac, Lily, Appleblossom, etc. as well as in fantasy creations.
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