| Identification | Back Directory | [Name]
(R)-(-)-CITRONELLYL BROMIDE | [CAS]
10340-84-8 | [Synonyms]
citronellyl bromide
(6R)-2,6-Dimethyl-2-octene
(R)-(-)-CITRONELLYL BROMIDE
8-BROMO-2,6-DIMETHYL-2-OCTENE
[R,(-)]-2,6-Dimethyl-2-octene
(R)-(-)-Citronellyl bromide 97%
(R)-(-)-Citronellyl bromide,97%
(6R)-8-bromo-2,6-dimethyloct-2-ene | [Molecular Formula]
C10H19Br | [MDL Number]
MFCD00134453 | [MOL File]
10340-84-8.mol | [Molecular Weight]
219.16 |
| Chemical Properties | Back Directory | [Boiling point ]
111 °C/12 mmHg (lit.) | [density ]
1.11 g/mL at 25 °C (lit.) | [refractive index ]
n20/D 1.474(lit.) | [Fp ]
203 °F | [storage temp. ]
2-8°C | [form ]
liquid | [Optical Rotation]
[α]20/D 6.8°, neat | [InChI]
1S/C10H19Br/c1-9(2)5-4-6-10(3)7-8-11/h5,10H,4,6-8H2,1-3H3/t10-/m1/s1 | [InChIKey]
QPKCDMXLSDFCQD-SNVBAGLBSA-N | [SMILES]
C[C@@H](CCBr)CC\C=C(/C)C |
| Hazard Information | Back Directory | [Uses]
(R)-(-)-Citronellylbromide can be used as a reactant to synthesize:
- (R)-3,7-dimethyloct-6-ene-1-amine via Gabriel synthesis which is then condensed with dicarboxylic acids to synthesize retro amides.
- Citronellyl derivatives of sulfoximines and sulfondiimines via alkylation using potassium hydroxide and dimethyl sulfoxide.
- Citronellyltriphenylphosphonium bromide which can be used as a key intermediate to synthesize (+)-caparratriene via Witting reaction.
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