ChemicalBook--->CAS DataBase List--->1072067-44-7

1072067-44-7

1072067-44-7 Structure

1072067-44-7 Structure
IdentificationBack Directory
[Name]

Ir[dFppy]2(dtbbpy)PF6
[CAS]

1072067-44-7
[Synonyms]

-κC]iridium hexafL
Ir[dFppy]2(dtbbpy)PF6
(Ir[dFppy]2(dtbpy))PF6
[4,4'-Bis(1,1-dimethyL
C]iridium hexafluorophosphate, 97%
)-2,2'-bipyridine-κN,κN]bis[3,5-difL
2-(2,4-difluorobenzene-6-id-1-yl)pyridine
[2,2'-bis (4-tert-butylpyridine)] bis [2- (2,4-difluorophenyl) pyridine] iridium (III) hexafluorophosphate
[4,4'-Bis(1,1-dimethylethyl)-2,2'-bipyridine-κN,κN]bis[3,5-difluoro-2-(2-pyridinyl-κN)phenyl-κC]iridium hexafluorophosphate, 97%
iridium(3+) ion bis(3,5-difluoro-2-(pyridin-2-yl)benzen-1-ide) 4-tert-butyl-2-(4-tert-butylpyridin-2-yl)pyridine hexafluoro-lambda5-phosphanuide
Ir[dFppy]2(dtbbpy)PF6,4,4'-Bis(1,1-dimethylethyl)-2,2'-bipyridine-κN,κN]bis[3,5-difluoro-2-(2-pyridinyl-κN)phenyl-κC]iridium hexafluorophosphate
[Molecular Formula]

C40H36F10IrN4P
[MDL Number]

MFCD31657504
[MOL File]

1072067-44-7.mol
[Molecular Weight]

985.93
Chemical PropertiesBack Directory
[Melting point ]

>300°C
[storage temp. ]

under inert gas (nitrogen or Argon) at 2-8°C
[form ]

powder or crystals
Safety DataBack Directory
[Symbol(GHS) ]


GHS07
[Signal word ]

Warning
[Hazard statements ]

H315-H319-H335
[Precautionary statements ]

P261-P264-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P337+P313-P362-P403+P233-P405-P501
Hazard InformationBack Directory
[Uses]

This photocatalyst readily facilitates alkynylation of carboxylic acids as well as the decarboxylative cross-coupling of oxalates via metallaphotoredox catalysis.
[reaction suitability]

core: iridium
reagent type: catalyst
reaction type: Photocatalysis
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