| Identification | Back Directory | [Name]
Ir[dFppy]2(dtbbpy)PF6 | [CAS]
1072067-44-7 | [Synonyms]
-κC]iridium hexafL
Ir[dFppy]2(dtbbpy)PF6
(Ir[dFppy]2(dtbpy))PF6
[4,4'-Bis(1,1-dimethyL
C]iridium hexafluorophosphate, 97%
)-2,2'-bipyridine-κN,κN]bis[3,5-difL
2-(2,4-difluorobenzene-6-id-1-yl)pyridine
[2,2'-bis (4-tert-butylpyridine)] bis [2- (2,4-difluorophenyl) pyridine] iridium (III) hexafluorophosphate
[4,4'-Bis(1,1-dimethylethyl)-2,2'-bipyridine-κN,κN]bis[3,5-difluoro-2-(2-pyridinyl-κN)phenyl-κC]iridium hexafluorophosphate, 97%
iridium(3+) ion bis(3,5-difluoro-2-(pyridin-2-yl)benzen-1-ide) 4-tert-butyl-2-(4-tert-butylpyridin-2-yl)pyridine hexafluoro-lambda5-phosphanuide
Ir[dFppy]2(dtbbpy)PF6,4,4'-Bis(1,1-dimethylethyl)-2,2'-bipyridine-κN,κN]bis[3,5-difluoro-2-(2-pyridinyl-κN)phenyl-κC]iridium hexafluorophosphate | [Molecular Formula]
C40H36F10IrN4P | [MDL Number]
MFCD31657504 | [MOL File]
1072067-44-7.mol | [Molecular Weight]
985.93 |
| Chemical Properties | Back Directory | [Melting point ]
>300°C | [storage temp. ]
under inert gas (nitrogen or Argon) at 2-8°C | [form ]
powder or crystals | [InChIKey]
YTFMVASKFDAIDY-UHFFFAOYSA-N | [SMILES]
[P+5]([F-])([F-])([F-])([F-])([F-])[F-].FC1C=C(F)C=[C-]2[Ir+3]34(N5=CC=CC=C5C5=C(C=C(F)C=[C-]35)F)(N3=CC=C(C(C)(C)C)C=C3C3=CC(C(C)(C)C)=CC=N43)N3=CC=CC=C3C=12 |
| Hazard Information | Back Directory | [Uses]
This photocatalyst readily facilitates alkynylation of carboxylic acids as well as the decarboxylative cross-coupling of oxalates via metallaphotoredox catalysis. | [reaction suitability]
core: iridium
reagent type: catalyst
reaction type: Photocatalysis |
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