| Identification | Back Directory | [Name]
1,3,2-DIOXATHIANE 2,2-DIOXIDE | [CAS]
1073-05-8 | [Synonyms]
NSC 526595
trimethylenesulfate
TRIMETHYLENESULPHATE
1,3-Propylenesulfate
Trimethylene sulfate
1,3-Propylene sulfate
1,3-PROPYLENESULPHATE
Propano-1,3-diyl sulfate
1,3-PROPYLENE SULFATE,98%
1,3,2-dioxathiane-2,2-dione
1,3,2-DIOXATHIANE 2,2-DIOXIDE
1,3-PROPANEDIOL CYCLIC SULFATE
1,3,2-Dioxathiane2,2-Dioxide>
1,3-Propanediol, cyclic sulphate
1,3-Propanediol cyclic sulfate 98%
1,3-Propanediol cyclic sulfate,1,3,2-Dioxathiane 2,2-dioxide | [EINECS(EC#)]
214-022-5 | [Molecular Formula]
C3H6O4S | [MDL Number]
MFCD00801144 | [MOL File]
1073-05-8.mol | [Molecular Weight]
138.14 |
| Chemical Properties | Back Directory | [Melting point ]
58-62 °C(lit.) | [Boiling point ]
153℃ (14 Torr) | [density ]
1.332 (estimate) | [vapor pressure ]
10Pa at 20℃ | [refractive index ]
1.5500 (estimate) | [storage temp. ]
Store at room temperature | [solubility ]
soluble in No data available | [form ]
solid | [Appearance]
White to off-white Solid | [InChI]
InChI=1S/C3H6O4S/c4-8(5)6-2-1-3-7-8/h1-3H2 | [InChIKey]
OQYOVYWFXHQYOP-UHFFFAOYSA-N | [SMILES]
O1CCCOS1(=O)=O | [LogP]
0.06 at 20℃ | [EPA Substance Registry System]
1,3,2-Dioxathiane, 2,2-dioxide (1073-05-8) |
| Safety Data | Back Directory | [Hazard Codes ]
Xn | [Risk Statements ]
40 | [Safety Statements ]
22-36 | [RIDADR ]
UN2811 | [WGK Germany ]
3 | [RTECS ]
TY4560000 | [TSCA ]
TSCA listed | [HazardClass ]
6.1 | [HS Code ]
2920901090 | [Storage Class]
11 - Combustible Solids | [Hazard Classifications]
Carc. 2
Eye Dam. 1
Muta. 2
Skin Sens. 1B |
| Hazard Information | Back Directory | [Uses]
1,3,2-Dioxathiane 2,2-Dioxide is a reagent used in the synthesis of deoxy salacinols via coupling reaction. | [General Description]
Bacillus sp. CCZU11-1 catalyzed biotransformation of 1,3-propanediol cyclic sulfate (1,3-PDS) and its derivatives has been proposed. It can undergo biocatalyzed transformation to diols by Rhodococcus sp. | [Flammability and Explosibility]
Notclassified | [Synthesis]
1,2-Diol/1,3-diol (50 mmol, 1.0 eq.) was dissolved in CH2Cl2 (30 mL) and the solution was cooled to 0°C. A solution of SOCl2 (65 mmol, 1.3 eq.) in CH2Cl2 (20 mL) was added via a charging funnel over 1 hr. The reaction mixture was heated to reflux for 1 h |
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