| Identification | Back Directory | [Name]
PROPAQUIZAFOP | [CAS]
111479-05-1 | [Synonyms]
AGIL
shogun
ro17-3664
Propaquiafop
PROPIQUIZAFOP
PROPAQUIZAFOP
PROPAQUIZAFOP 10%EC
Propaquizafop Standard
Propaquizafop Solution
PROPAQUIZAFOP PESTANAL, 250 MG
(r)-lidene)amino)oxy)ethyleste
Propaquizafop@100 μg/mL in Methanol
Propaquizafop@1000 μg/mL in Acetonitrile
propaquizafop (bsi, draft e-iso, draft f-iso)
Propaquiafop Solution in Acetonitrile, 1000μg/mL
(R)-2-(propan-2-ylideneaMinooxy)ethyl 2-(4-(6-chloroquinoxalin-2
2-(4-((6-chloro-2-quinoxalinyl)oxy)phenoxy)-propanoicaci2-(((1-methylethy
2-isopropylideneamino-oxyethyl(r)-2-(4-(6-chloroquinoxalin-2-yloxy)phenoxy)p
2-isopropylideneaminooxyethyl(R)-2-(4-(6-chloroquinoxalin-2-yloxy)phenoxy)propionate
(R)-2-(propan-2-ylideneaminooxy)ethyl 2-(4-(6-chloroquinoxalin-2-yloxy)phenoxy)propanoate
(R)-2(((1-methylethylidene)amino)oxy)ethyl-2-(4-((6-chloro-2-quinoxalinyl)oxy)phenoxy)propanoate
Propanoic acid, 2-[4-[(6-chloro-2-quinoxalinyl)oxy]phenoxy]-, 2-[[(1-methylethylidene)amino]oxy]ethyl ester, (2R)- | [Molecular Formula]
C22H22ClN3O5 | [MDL Number]
MFCD01697482 | [MOL File]
111479-05-1.mol | [Molecular Weight]
443.88 |
| Chemical Properties | Back Directory | [Melting point ]
62-64° | [alpha ]
D20 +29.7° (c = 0.93% in chloroform) | [Boiling point ]
582.7±60.0 °C(Predicted) | [density ]
d20 1.29 | [refractive index ]
1.6500 (estimate) | [Fp ]
>100 °C | [storage temp. ]
0-6°C | [solubility ]
Chloroform (Slightly), Ethyl Acetate (Slightly) | [form ]
neat | [pka]
-1.41±0.48(Predicted) | [color ]
White | [Water Solubility ]
627ug/L(temperature not stated) | [Merck ]
13,7898 | [Henry's Law Constant]
3.2×106 mol/(m3Pa) at 25℃, Duchowicz et al. (2020) | [Major Application]
agriculture
environmental | [InChI]
1S/C22H22ClN3O5/c1-14(2)26-29-11-10-28-22(27)15(3)30-17-5-7-18(8-6-17)31-21-13-24-20-12-16(23)4-9-19(20)25-21/h4-9,12-13,15H,10-11H2,1-3H3/t15-/m1/s1 | [InChIKey]
FROBCXTULYFHEJ-OAHLLOKOSA-N | [SMILES]
C[C@@H](Oc1ccc(Oc2cnc3cc(Cl)ccc3n2)cc1)C(=O)OCCO\N=C(\C)C | [LogP]
4.600 | [EPA Substance Registry System]
Propanoic acid, 2-[4-[(6-chloro-2-quinoxalinyl)oxy]phenoxy]-, 2-[[(1-methylethylidene)amino]oxy]ethyl ester, (2R)- (111479-05-1) |
| Safety Data | Back Directory | [Hazard Codes ]
Xn | [Risk Statements ]
20 | [Safety Statements ]
22 | [RIDADR ]
3077 | [WGK Germany ]
2 | [RTECS ]
UA2458258 | [HazardClass ]
9 | [PackingGroup ]
III | [HS Code ]
29339900 | [Storage Class]
11 - Combustible Solids | [Hazard Classifications]
Aquatic Acute 1
Aquatic Chronic 1
Skin Sens. 1B | [Toxicity]
LD50 in rats (mg/kg): >5000 orally; >2000 dermally (Bocion) |
| Hazard Information | Back Directory | [Chemical Properties]
Whoa ester is colorless crystal (industrial product is orange or brown powder), melting point 66.3 ℃, 260 ℃ decomposition. Relative density 1.35(20℃), vapor pressure 4.4×10-7 mPa(25℃). Distribution coefficient Koclg P=4.78(25℃).Henry's constant 9.2×10-8Pa-m3/mol.Solubility in water(25℃)0.63g/m3;Solubility in other solvents(25℃,g/L):Acetone,Dichloromethane,Ethyl acetate,Toluene>500,Methanol76,n-Octanol30,n-Hexane11.At room temperature,closed Stable ≥2y in a closed container at room temperature; Hydrolysis DT50 (25°C): 10.5d (pH 5), 32d (pH 7), 12.9h (pH 9). pKa is stable to UV. Stable to UV. pKa2.3. | [Uses]
Herbicide. | [Definition]
ChEBI: A quinoxaline derivative used as systemic herbicide for annual and perennial grasses. | [Production Methods]
The production of propaquizafop involves a multi-step synthesis beginning with 2,6-dichloroquinoxaline as the core starting material. This compound undergoes sequential reactions with acetone, hydroxylamine hydrochloride, ethylene oxide, hydroquinone, thionyl chloride, and formamide to build the complex molecular structure of propaquizafop, a selective post-emergence herbicide. | [Mechanism of action]
Systemic, absorbed by foliage and roots and translocated. Acetyl CoA carboxylase inhibitor (ACCase) - distrupts fatty acid biosynthesis and lipid formation. | [Pesticide Type]
Herbicide |
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| Company Name: |
J & K SCIENTIFIC LTD.
|
| Telephone: |
18210857532 18210857532 |
| Website: |
https://www.jkchemical.com |
| Company Name: |
Tocopharm Co., Ltd.
|
| Telephone: |
+86-021-69895597 13776836200 +86-13776836200 |
| Website: |
http://www.tocopharm.com/ |
| Company Name: |
Xi'an MC Biotech, Co., Ltd.
|
| Telephone: |
029-89275612 +8618991951683 |
| Website: |
www.chemicalbook.com/ShowSupplierProductsList1759320/0_EN.htm |
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