| Identification | Back Directory | [Name]
TETRAPROPYLAMMONIUM PERRUTHENATE | [CAS]
114615-82-6 | [Synonyms]
TPAP
TerapropylaMMoniuMperruthenate
TETRAPROPYLAMMONIUM PERRUTHENATE
TETRA-N-PROPYLAMMONIUM PERRUTHENATE
TetrapropylaMMoniuM perruthenate 97%
tetrapropylammonium perruthenate(VII)
Tetrapropylammonium tetraoxoruthenate
Tetrapropylammonium Perruthenate (TPAP)
TETRA-N-PROPYLAMMONIUM PERRUTHENATE (VII)
Tetrapropylammonium perruthenate, min. 97%
Tetrapropylammoniumperruthenate,min.97%TPAP
Tetra-n-propylammonium perruthenate(VII), 98+%
Tetra n-propylammonium perruthenate Oxidation
TetrapropylaMMoniuM perruthenate,TPAP,(n-C3H7)NRuO4
TetrapropylaMMoniuM perruthenate,97% TPAP, (n-C3H7)4NRuO4
1-Propanaminium, N,N,N-tripropyl-, (T-4)-tetraoxoruthenate(1-) | [EINECS(EC#)]
-0 | [Molecular Formula]
C12H28NO4Ru | [MDL Number]
MFCD00074914 | [MOL File]
114615-82-6.mol | [Molecular Weight]
351.43 |
| Chemical Properties | Back Directory | [Appearance]
dark green solid | [Melting point ]
~160 °C (dec.)(lit.)
| [storage temp. ]
2-8°C
| [solubility ]
Methanol (Slightly) | [form ]
crystal | [color ]
green | [Water Solubility ]
Insoluble in water. | [Sensitive ]
Hygroscopic | [Stability:]
store cold | [InChI]
InChI=1S/C12H28N.4O.Ru/c1-5-9-13(10-6-2,11-7-3)12-8-4;;;;;/h5-12H2,1-4H3;;;;;/q+1;;;;;-1 | [InChIKey]
NQSIKKSFBQCBSI-UHFFFAOYSA-N | [SMILES]
[N+](CCC)(CCC)(CCC)CCC.[Ru-](=O)(=O)(=O)=O |
| Hazard Information | Back Directory | [Chemical Properties]
dark green solid | [Definition]
ChEBI: A quaternary ammonium salt having tetrapropylammonium as the cation and perruthenate as the anion. | [General Description]
Tetrapropylammonium perruthenate is a mild oxidizing agent used for the oxidation of alcohols to corresponding carbonyl compounds. It is a non-volatile, air-stable, and readily soluble reagent, which can be used either stoichiometrically or catalytically with a suitable co-oxidant. | [reaction suitability]
reagent type: oxidant | [Purification Methods]
It is a strong oxidant and may explode on heating. It can be washed with aqueous n-propanol, then H2O and dried over KOH in a vacuum. It is stable at room temperature but best stored in a refrigerator. It is soluble in CH2Cl2 and MeCN. [Dengel et al. Transition Met Chem 10 98 1985, Griffith et al. J Chem Soc, Chem Commun 1625 1987.] § Polymer supported reagent is available commercially. |
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