| Identification | Back Directory | [Name]
(chlorodifluoroMethyl)triMethylsilane | [CAS]
115262-00-5 | [Synonyms]
Chlordifluormethyltrimethylsilan
(chlorodifluoroMethyl)triMethylsilane
Silane, (chlorodifluoromethyl)trimethyl- | [Molecular Formula]
C4H9ClF2Si | [MDL Number]
MFCD20486786 | [MOL File]
115262-00-5.mol | [Molecular Weight]
158.65 |
| Hazard Information | Back Directory | [Uses]
(Chlorodifluoromethyl)trimethylsilane, is one of the partially fluorinated compounds, which are often used for diverse applications in materials science, agrochemistry, and the pharmaceutical industry. | [Reactions]
(1) Difluoromethylenation of alkenes.
Refs. 1) Angew. Chem. Int. Ed. 2011, 50, 7153 –7157; 2) Chem. Commun. 2011, 47, 2411–2413.
(2) Difluoromethylenation of alkynes.
Refs. 1) Angew. Chem. Int. Ed. 2011, 50, 7153 –7157; 2) Chem. Commun. 2011, 47, 2411–2413.
(3) Difluoromethylenation of TMSCN.
Ref. J. Org. Chem. 2012, 77, 5850?5855.
(4) Difluoromethylenation of benzyl and alkylzinc halides.
Ref. Org. Lett. 2013, 15, 917 – 919.
(5) Fluorination aminocarbonylation of aldehydes
Ref. Angew. Chem. Int. Ed. 2022, e202115467
| [References]
[1]Angewandte Chemie International Edition.DOI :10.1002/anie.202283811
[2]The Journal of Organic Chemistry.DOI :10.1021/acs.orglett.2c02899
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