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1186392-43-7

1186392-43-7 Structure

1186392-43-7 Structure
IdentificationBack Directory
[Name]

(2R)-1-(11bR)-(Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-yl)-2-Methyl-1,2,3,4-tetrahydroquinoline, 98%
[CAS]

1186392-43-7
[Synonyms]

(R,Ra)-Me-THQphos
(2R)-1-(11bR)-Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosph epin-4-yl-1,2,3,4-tetrahydro-2-methylquinoline
(2R)-1-(11bR)-(Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-yl)-2-Methyl-1,2,3,4-tetrahydroquinoline, 98%
[Molecular Formula]

C30H24NO2P
[MDL Number]

MFCD28144549
[MOL File]

1186392-43-7.mol
[Molecular Weight]

461.491
Chemical PropertiesBack Directory
[Melting point ]

210-212 °C
[Boiling point ]

654.3±48.0 °C(Predicted)
[form ]

Powder
[pka]

1.35±0.40(Predicted)
[color ]

yellow
[Sensitive ]

moisture sensitive
[InChIKey]

YFCZGDQGHCIHNB-XKGZFIRZNA-N
[SMILES]

N1(P2OC3=CC=C4C(=C3C3=C5C(C=CC=C5)=CC=C3O2)C=CC=C4)C2=C(C=CC=C2)CC[C@H]1C |&1:32,r|
[CAS DataBase Reference]

1186392-43-7
Questions And AnswerBack Directory
[Reaction]

  1. Chiral ligand used in the iridium-catalyzed formation of a chiral five-membered ring spiroindolenine.
  2. Chiral ligand used in an iridium-catalyzed, enantioselective, allylic alkylation reaction.
  3. Chiral ligand used in the iridium-catalyzed, enantioselective functional group substitution at the α-position of β-ketoesters.
Reactions of 1186392-43-7
Spectrum DetailBack Directory
[Spectrum Detail]

(2R)-1-(11bR)-(Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-yl)-2-Methyl-1,2,3,4-tetrahydroquinoline, 98%(1186392-43-7)1HNMR
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