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1188-14-3

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1188-14-3 Structure

1188-14-3 Structure
IdentificationBack Directory
[Name]

TRIETHYLGERMANIUM HYDRIDE
[CAS]

1188-14-3
[Synonyms]

TRIETHYLGERMANE
TRIETHYLGERMANIUM HYDRIDE
Triethylgermanium hydride,98%
[Molecular Formula]

C6H16Ge
[MDL Number]

MFCD00077989
[MOL File]

1188-14-3.mol
[Molecular Weight]

160.83
Chemical PropertiesBack Directory
[Appearance]

clear colorless liquid
[Boiling point ]

121-122 °C20 mm Hg(lit.)
[density ]

0.994 g/mL at 25 °C(lit.)
[refractive index ]

n20/D 1.433(lit.)
[Fp ]

47 °F
[storage temp. ]

Flammables area
[form ]

liquid
[Specific Gravity]

1.004
[Water Solubility ]

Soluble in water( 46 g/100 mL (26°C).
[Hydrolytic Sensitivity]

7: reacts slowly with moisture/water
[InChI]

1S/C6H16Ge/c1-4-7(5-2)6-3/h7H,4-6H2,1-3H3
[InChIKey]

LTLGQZPDSQYFSB-UHFFFAOYSA-N
[SMILES]

CC[GeH](CC)CC
Hazard InformationBack Directory
[Chemical Properties]

clear colorless liquid
[Uses]

Co-reactant for the preparation of germanium acrylates. They are the Synthetic Reagents.
[General Description]

Triethylgermanium hydride (Ge(C2H5)3H) may be prepared by a three step process:
  • Ge(C2H5)3Br reacted with Na to yield Ge2(C2H5)6
  • Ge2(C2H5)6 treated with Li to form Ge(C2H5)3Li
  • ammonolysis of Ge(C2H5)3Li to give the end product, Ge(C2H5)3H. 1
[reaction suitability]

core: germanium
reagent type: reductant
Safety DataBack Directory
[Hazard Codes ]

F,Xn
[Risk Statements ]

11-20/21/22
[Safety Statements ]

16-36
[RIDADR ]

UN 1993 3/PG 2
[WGK Germany ]

3
[TSCA ]

No
[HazardClass ]

4.3
[PackingGroup ]

II
[Storage Class]

3 - Flammable liquids
[Hazard Classifications]

Acute Tox. 4 Dermal
Acute Tox. 4 Inhalation
Acute Tox. 4 Oral
Flam. Liq. 2
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