| Identification | Back Directory | [Name]
METHYLENECYCLOHEXANE | [CAS]
1192-37-6 | [Synonyms]
methylene-cyclohexan
METHYLENECYCLOHEXANE
Methycenecyclohexane
1-Methylenecyclohexane
cyclohexane,methylene-
Methylenecyclohexane,98%
Methylenecyclohexane,99+%
Methylenecyclohexane, 98% 1GR | [EINECS(EC#)]
214-752-4 | [Molecular Formula]
C7H12 | [MDL Number]
MFCD00001661 | [MOL File]
1192-37-6.mol | [Molecular Weight]
96.17 |
| Chemical Properties | Back Directory | [Appearance]
colourless liquid | [Melting point ]
-106.7°C | [Boiling point ]
102-103 °C(lit.)
| [density ]
0.8 g/mL at 25 °C(lit.)
| [refractive index ]
n20/D 1.449(lit.)
| [Fp ]
20 °F
| [storage temp. ]
0-6°C | [form ]
Liquid | [color ]
Clear colorless | [Stability:]
Stable. Highly flammable. Incompatible with strong oxidizing agents. Refrigerate. | [BRN ]
773760 | [InChI]
1S/C7H12/c1-7-5-3-2-4-6-7/h1-6H2 | [InChIKey]
YULMNMJFAZWLLN-UHFFFAOYSA-N | [SMILES]
C=C1CCCCC1 | [EPA Substance Registry System]
Cyclohexane, methylene- (1192-37-6) |
| Hazard Information | Back Directory | [Chemical Properties]
colourless liquid | [Uses]
Methylenecyclohexane is excellent building block for organic molecules. | [Synthesis Reference(s)]
Journal of the American Chemical Society, 100, p. 3611, 1978 DOI: 10.1021/ja00479a061
The Journal of Organic Chemistry, 48, p. 326, 1983 DOI: 10.1021/jo00151a010
Tetrahedron Letters, 25, p. 4901, 1984 DOI: 10.1016/S0040-4039(01)91254-7 | [General Description]
Methylenecyclohexane ring is obtained by 1,4-addition of 4-pentenylmagnesium bromide to 2-cyano-2-cycloalkenones followed by a Pd(II)-mediated oxidative cyclization. It undergoes gas phase ozonolysis to form secondary organic aerosol (SOA). |
| Safety Data | Back Directory | [Hazard Codes ]
F,Xn | [Risk Statements ]
11-65 | [Safety Statements ]
16-23-24/25-62 | [RIDADR ]
UN 3295 3/PG 2
| [WGK Germany ]
3
| [TSCA ]
TSCA listed | [HazardClass ]
3.1 | [PackingGroup ]
II | [HS Code ]
29021900 | [Storage Class]
3 - Flammable liquids | [Hazard Classifications]
Asp. Tox. 1
Flam. Liq. 2 |
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