| Identification | Back Directory | [Name]
Chlorobis(ethylene)rhodium (I) dimer | [CAS]
12081-16-2 | [Synonyms]
[Rh(C2H4)2Cl]2
Chlorobis(ethylene)r
Bis[chlorodiethylenerhodium]
Divinylrhodium chloride dimer
Dichlorotetra(ethene)dirhodium
Bis[chlorobis(ethylene)rhodiuM]
Diethylenerhodium chloride dimer
Chlorobis(ethylene)rhodium dimer
U-dichlorotetraethylene dirhodium
Dichlorotetrakis(ethene)dirhodium
Chlorobis(ethylene)rhodium(I) dime
Tetrakis(ethylene)dichlorodirhodium
U-DICHLOROTETRAETHYLENEDIRHODIUM(I)
-Dichlorotetraethylene dirhodium(I)
mhu-dichlorotetraethylene dirhodium
CHLOROBIS(ETHYLENE)RHODIUM (I) DIMER
á-Dichlorotetraethylene dirhodiuM(I)
MU-DICHLOROTETRAETHYLENE DIRHODIUM(I)
Dichlorotetrakis-(ethylene)-dirhodium
Chlorobis(ethylene)rhodium(I)dimer,99%
BIS(ETHYLENE)RHODIUM(I) CHLORIDE DIMER
DICHLOROTETRAKIS(ETHYLENE)DIRHODIUM(I)
Di-Mu-chlorotetraethylene dirhodiuM(I)
Dichlorotetraethylene dirhodiuM(I) 100MG
TETRAKIS(ETHYLENE)DIRHODIUM(I) DICHLORIDE
Micron-Dichlorotetraethylene dirhodium(I)
DI-MY-CHLOROTETRAKIS(ETHYLENE)DIRHODIUM(I)
RhodiuM, di-M-chlorotetrakis(h2-ethene)di-
di-mu-chlorotetrakis(eta2-ethylene)dirhodium
Rhodium, di-.mu.-chlorotetrakis(.eta.2-ethene)di-
Chlorobis(ethylene)rhodiuM(I) diMer,98% [Rh(C2H4)2Cl]2
Bis(ethylene)rhodium(I) chloride dimer (53% Rh) for synthesis
Di(chloro)tetrakis(-ethylene)dirhodium(I) Store refrigerated Keep under ethylene atmosphere | [EINECS(EC#)]
235-145-0 | [Molecular Formula]
C8H16Cl2Rh2 | [MDL Number]
MFCD00013206 | [MOL File]
12081-16-2.mol | [Molecular Weight]
388.93 |
| Chemical Properties | Back Directory | [Appearance]
red-brown powder | [storage temp. ]
-20°C | [solubility ]
Chloroform (Slightly, Heated, Sonicated), DMSO (Slightly, Heated, Sonicated), Me | [form ]
Crystalline Powder or Chunks | [color ]
Rust | [Water Solubility ]
Sparingly soluble in ethanol, acetone, dioxane, chloroform and dichloromethane. Insoluble in water. | [Sensitive ]
Air Sensitive | [Exposure limits]
ACGIH: TWA 0.01 mg/m3; TWA 1 mg/m3
NIOSH: IDLH 2 mg/m3; IDLH 100 mg/m3; TWA 0.001 mg/m3; TWA 0.1 mg/m3 | [Stability:]
Air Sensitive | [InChI]
InChI=1S/4C2H4.2ClH.2Rh/c4*1-2;;;;/h4*1-2H2;2*1H;;/q;;;;;;2*+1/p-2 | [InChIKey]
OOQJCPOXJFCGCR-UHFFFAOYSA-L | [SMILES]
C=C.C=C.C=C.C=C.Cl[Rh].Cl[Rh] |
| Hazard Information | Back Directory | [Chemical Properties]
red-brown powder | [Uses]
Chlorobis(ethylene)rhodium(I) dimer is used as a precursor to rhodium(I) norbornadiene catalyst, which is used in an asymmetric 1,4-addition of arylboronic acids to cyclic enones. Further, it serves as an important organic intermediate. It catalyzes the dimerization of ethylene to 1-butene. It is also used in the preparation of homogeneous catalysts. | [reaction suitability]
core: rhodium
reagent type: catalyst | [Synthesis]
The synthesis of di(vinyl)chlororhodium dimers was first reported by Cramer, Richard in Inorganic
Chemistry, 1,722-3, where they dissolved RhCl3-(H2O)X in methanol and then passed it through
ethylene gave an orange-red powder product in about 70% yie |
|
| Company Name: |
LaaJoo Gold
|
| Telephone: |
021-60702684 18516024827 |
| Website: |
www.chemicalbook.com/ShowSupplierProductsList20079/0_EN.htm |
| Company Name: |
J & K SCIENTIFIC LTD.
|
| Telephone: |
18210857532 18210857532 |
| Website: |
https://www.jkchemical.com |
| Company Name: |
Alfa Aesar
|
| Telephone: |
400-6106006 |
| Website: |
http://chemicals.thermofisher.cn |
| Company Name: |
Aemon Chemical
|
| Telephone: |
0086-755-86198205 |
| Website: |
www.aemonchem.com |
| Company Name: |
Spectrum Chemical Manufacturing Corp.
|
| Telephone: |
021-021-021-67601398-809-809-809 15221380277 |
| Website: |
www.spectrumchemical.com/oa_html/index.jsp?minisite=10020&respid=22372&language=us |
| Company Name: |
T&W GROUP
|
| Telephone: |
021-61551611 13296011611 |
| Website: |
www.trustwe.com/ |
|