ChemicalBook--->CAS DataBase List--->121309-88-4

121309-88-4

121309-88-4 Structure

121309-88-4 Structure
IdentificationBack Directory
[Name]

BENZYLTRIMETHYLAMMONIUM TETRACHLOROIODATE
[CAS]

121309-88-4
[Synonyms]

Benzyltrimethylaminium
Trimethylbenzylaminium
chlorinatingreagent]95+%
Dimethyl(benzyl)(methyl)aminium
N,N,N-Trimethylbenzenemethanaminium
Benzyltrimethylammonium trichloroiodide
BENZYLTRIMETHYLAMMONIUM &
BENZYLTRIMETHYLAMMONIUM TETRACHLOROIODATE
N-Benzyl-N,N,N-trimethylammonium tetrachloroiodate
Benzyltrimethylammonium tetrachloroiodate purum, >=98.0% (AT)
Benzyltrimethylammonium Tetrachloroiodate [Chlorinating Reagent]
Benzyltrimethylammonium Tetrachloroiodate [Chlorinating Reagent]>
[Molecular Formula]

C10H16Cl4IN
[MDL Number]

MFCD00191607
[MOL File]

121309-88-4.mol
[Molecular Weight]

418.96
Chemical PropertiesBack Directory
[Melting point ]

106-125 °C
[solubility ]

sol MeCN, MeNO3, DMSO, DMF; slightly sol MeOH, EtOH, AcOH, AcOEt, CHCl3, CH2Cl2; insol C6H14, CCl4, C6H6, H2O.
[form ]

powder to crystal
[color ]

Light yellow to Brown
[BRN ]

4619219
[CAS DataBase Reference]

121309-88-4
Safety DataBack Directory
[Hazard Codes ]

C
[Risk Statements ]

34
[Safety Statements ]

26-36/37/39-45
[RIDADR ]

UN 1759 8/PG 2
[WGK Germany ]

3
[F ]

4.4-8
[HazardClass ]

8
[PackingGroup ]

III
[HS Code ]

29239000
Hazard InformationBack Directory
[Uses]

Benzyltrimethylammonium tetrachloroiodate is a chlorinating agent for aromatic compounds; it can be used for side chain chlorination of aromatic compounds and chlorine addition of olefins.
[Preparation]

Chlorine gas was passed into a solution of benzyltrimethylammonium chloride (18.6 g, 0.1 mol) and iodine (12.7 g, 0.05 mol) in CH2Cl2 (300 mL) for 15 min; the yield of BEnzyltrimethylammonium tetrachloroiodate was 40 g (95%).
[storage]

Stable solid, but gradually decomposes with evolution of Cl2 when in contact with air for a long time. This reagent should be handled in a fume hood.
Spectrum DetailBack Directory
[Spectrum Detail]

BENZYLTRIMETHYLAMMONIUM TETRACHLOROIODATE(121309-88-4)1HNMR
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