| Identification | Back Directory | [Name]
ETA-BENZENE(ETA-CYCLOPENTADIENYL)IRON HEXAFLUOROPHOSPHATE | [CAS]
12176-31-7 | [Synonyms]
BENZENECYCLOPENTADIENYLIRON(II) HEXAFLU&
benzeneethacyclopentadienylironhexaflurophosphate
ETA-BENZENE(ETA-CYCLOPENTADIENYL)IRON HEXAFLUOROPHOSPHATE
η-Benzene(η-cyclopentadienyl)iron(II) Hexafluorophosphate
etha-Benzene(etha-cyclopentadienyl)iron Hexaflurophosphate
(η6-Benzene)(η5-cyclopentadienyl)iron(Ⅱ) Hexafluorophosphate
eta-Benzene(eta-cyclopentadienyl)iron(II) Hexafluorophosphate | [Molecular Formula]
C11H11F6FeP 5* | [MDL Number]
MFCD01631295 | [MOL File]
12176-31-7.mol | [Molecular Weight]
344.01 |
| Chemical Properties | Back Directory | [Melting point ]
268 °C (dec.)(lit.)
| [form ]
solid
| [color ]
yellow | [Water Solubility ]
insol H2O, Et2O, THF; sol acetone, MeCN; mod sol CH2Cl2. | [InChI]
1S/C6H6.C5H5.F6P.Fe/c1-2-4-6-5-3-1;1-2-4-5-3-1;1-7(2,3,4,5)6;/h1-6H;1-5H;;/q;;-1;+1 | [InChIKey]
ZFDATMJBJWNTMT-UHFFFAOYSA-N | [SMILES]
[Fe+].[CH]1[CH][CH][CH][CH]1.[CH]2[CH][CH][CH][CH][CH]2.F[P-](F)(F)(F)(F)F |
| Hazard Information | Back Directory | [Uses]
Catalyst for:
- Nitroxide-mediated photochemical-living radical polymerization reactions
- Assembly of complex photonic crystals
- Preparation of cyclopentadien-iron-biphenyl hexafluorophosphate ([Cp-Fe-biphenyl]+PF6-) for cationic photopolymerization of epoxy systems
Reactant for:
- LIgand exchange reactions
- Solid-state synthesis of carbon nanostructures
| [reaction suitability]
reagent type: catalyst
core: iron | [Precautions]
[(C6H6)FeCp]PF6 is air stable. No special storage requirements are indicated. Its toxicity is unreported, but is probably low to moderate.
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| Company Name: |
Energy Chemical
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| Tel: |
021-021-58432009 400-005-6266 |
| Website: |
http://www.energy-chemical.com |
| Company Name: |
Sigma-Aldrich
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021-61415566 800-8193336 |
| Website: |
https://www.sigmaaldrich.cn |
| Company Name: |
Merck KGaA
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| Tel: |
21-20338288 |
| Website: |
www.sigmaaldrich.cn |
| Company Name: |
A.J Chemicals
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| Tel: |
91-9810153283 |
| Website: |
www.ajchemicals.com |
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