ChemicalBook--->CAS DataBase List--->1219080-77-9

1219080-77-9

1219080-77-9 Structure

1219080-77-9 Structure
IdentificationBack Directory
[Name]

2-(Di-1-adamantylphosphino) dimethylaminobenzene,97% Me-DalPhos
[CAS]

1219080-77-9
[Synonyms]

Me-Dalphos
97% Me-DalPhos
Di(1-adamantyl)-2-dimethylaminophenylphosphine
2-(Di-1-adaMantylphosphino)diMethylaMinobenzene
2-(Di-1-adamantylphosphino)-N,N-dimethylaniline
Bis(adamant-1-yl)(2-dimethylaminophenyl)phosphine
Di(1-adamantyl)-2-dimethylaminophenylphosphine 98%
2-(Di-1-adamantylphosphino) dimethylaminobenzene,97% Me-DalPhos
2-[Bis(tricyclo[3.3.1.13,7]dec-1-yl)phosphino]-N,N-dimethylbenzeneamine
[Molecular Formula]

C28H40NP
[MDL Number]

MFCD17018758
[MOL File]

1219080-77-9.mol
[Molecular Weight]

421.598
Chemical PropertiesBack Directory
[Melting point ]

237-242°C
[storage temp. ]

2-8°C, protect from light, stored under nitrogen
[form ]

crystal
[pka]

4.67±0.18(Predicted)
[color ]

white to yellow
[Sensitive ]

air sensitive
[InChIKey]

MILNYLCUWRWYBI-XMCXLQRDSA-N
[SMILES]

CN(C)c1ccccc1P([C@@]23C[C@@H]4C[C@@H](C[C@@H](C4)C2)C3)[C@@]56C[C@@H]7C[C@@H](C[C@@H](C7)C5)C6
Safety DataBack Directory
[Symbol(GHS) ]

GHS hazard pictograms
GHS07
[Signal word ]

Warning
[Hazard statements ]

H315-H319-H335
[Precautionary statements ]

P261-P264-P271-P280-P302+P352-P305+P351+P338
[Hazard Codes ]

Xi
[Risk Statements ]

36/37/38
[Safety Statements ]

26
[WGK Germany ]

3
[Storage Class]

11 - Combustible Solids
[Hazard Classifications]

Eye Irrit. 2
Skin Irrit. 2
STOT SE 3
Questions And AnswerBack Directory
[Reaction]

Versatile ligand for the palladium-catalyzed amination of aryl and heteroaryl chlorides with primary aryl and alkylamines, cyclic and acyclic amines, lithium amide, N-H imines, hydrazones and ammonia.
  Reactions of 1219080-77-9
Hazard InformationBack Directory
[Uses]

2-(Di-1-adamantylphosphino)dimethylaminobenzene is a ligand employed in Pd-?catalyzed cross-?coupling reactions.
[reaction suitability]

reagent type: ligand
reaction type: Buchwald-Hartwig Cross Coupling Reaction
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