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1221746-66-2

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1221746-66-2 Structure

1221746-66-2 Structure
IdentificationBack Directory
[Name]

(RP)-1-[(S)-1-(Di-tert-butylphosphino)ethyl]-2-[(S)-phenylphosphinoyl]ferrocene
[CAS]

1221746-66-2
[Synonyms]

JoSPOphos SL-J688-2
(S,R(p),S(SPO)-1-Phenylphosphinoyl)-2-[1-(tert-butylphosphino)ethyl]-ferrocene
(RP)-1-[(S)-1-(Di-tert-butylphosphino)ethyl]-2-[(S)-phenylphosphinoyl]ferrocene
(RP)-1-[(S)-1-(Di-tert-butylphosphino)ethyl]-2-[(S)-phenylphosphinoyl]ferrocene >=97%
(R,S(p), R(SPO)-1-Phenylphosphinoyl)-2-[1-(t-butylphosphino)ethyl]ferrocene, Min. 97% JoSPOphos
(S, R(p), S(SPO)-1-Phenylphosphinoyl)-2-[1-(t-butylphosphino)ethyl]ferrocene, Min. 97% JoSPOphos
(2S)-1-[(1S)-1-[Bis(1,1-dimethylethyl)phosphino]ethyl]-2-[(S)-phenylphosphinyl]ferrocene (acc to CAS)
[Molecular Formula]

C26H36FeOP2
[MDL Number]

MFCD19105637
[MOL File]

1221746-66-2.mol
[Molecular Weight]

476.32
Chemical PropertiesBack Directory
[storage temp. ]

under inert gas (nitrogen or Argon) at 2-8°C
[form ]

Powder
[color ]

orange
[Stability:]

store cold
[InChI]

1S/C21H31OP2.C5H5.Fe/c1-16(24(20(2,3)4)21(5,6)7)18-14-11-15-19(18)23(22)17-12-9-8-10-13-17;1-2-4-5-3-1;/h8-16,23H,1-7H3;1-5H;/t16-;;/m0../s1
[InChIKey]

ZRFUSACJLNCGTO-SQKCAUCHSA-N
[SMILES]

[Fe].[CH]1[CH][CH][CH][CH]1.C[C@@H]([C]2[CH][CH][CH][C]2[P@H](=O)c3ccccc3)P(C(C)(C)C)C(C)(C)C
Hazard InformationBack Directory
[Chemical Properties]

Yellow powder
[General Description]

sold in collaboration with Solvias AG
Safety DataBack Directory
[Symbol(GHS) ]

Exclamation Mark (GHS07)
GHS07
[Signal word ]

Warning
[Hazard statements ]

H302-H315-H319-H335
[Precautionary statements ]

P261-P280-P301+P312-P302+P352-P305+P351+P338
[WGK Germany ]

3
[HS Code ]

29319090
[Storage Class]

11 - Combustible Solids
Questions And AnswerBack Directory
[Reaction]

  1. Ligands used for the rhodium-catalyzed asymmetric hydrogenation of functionalized alkenes, α- and β- ketoesters.
  2. Ligand for rhodium -catalyzed enantioselective formation of tertiary and quaternary allylic C–N bonds via allylation of tetrazoles.
  3. Ligand for rhodium-catalyzed highly regio- and enantioselective addition of pyrazoles to terminal allenes.
Reactions of 1221746-66-2_1
Reactions of 1221746-66-2_2
Spectrum DetailBack Directory
[Spectrum Detail]

(RP)-1-[(S)-1-(Di-tert-butylphosphino)ethyl]-2-[(S)-phenylphosphinoyl]ferrocene(1221746-66-2)1HNMR
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