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12245-39-5

12245-39-5 Structure

12245-39-5 Structure
IdentificationBack Directory
[Name]

ACETYLACETONATO(1,5-CYCLOOCTADIENE)RHODIUM(I)
[CAS]

12245-39-5
[Synonyms]

rh(acac)(cod)
Acetylacetonato(1,5-
(ACETYLACETONATO)(1,5-CYCLOOCTADIENE)RH&
acetylacetonate-1,5-cyclooctadienerhodium
ACETYLACETONATO(1,5-CYCLOOCTADIENE)RHODIUM(I)
(1,5-cyclooctadiene)(2,4-pentanedionato)-rhodiu
(1,5-cyclooctadiene)(2,4-pentanedionato)rhodium
RHODIUM (1,5-CYCLOOCTADIENE)-2,4-PENTANEDIONATE
(Acetylacetonato)(1,5-cyclooctadiene)rhodium(Ⅰ)
(1,5-Cyclooctadiene)rhodium(I) 2,4-pentanedionate
Acetylacetonato(1,5-cyclooctadiene)rhodium(I),97%
Acetylacetonato(1,5-cyclooctadiene)rhodium(I),98%
(1,5-cyclooctadiene)(2,4-pentanedionato)rhodium(I)
(ACETYLACETONATO)(ETA-CYCLOOCTA-1,5-DIENE)RHODIUM (I)
((1,2,5,6-eta)-1,5-cyclooctadiene)(2,4-pentanedionato-o,o’)-rhodiu
[Molecular Formula]

C13H19O2Rh
[MDL Number]

MFCD00075046
[MOL File]

12245-39-5.mol
[Molecular Weight]

310.19
Chemical PropertiesBack Directory
[Appearance]

Orange crystal
[Melting point ]

138-140 °C(lit.)
[storage temp. ]

below 5° C
[form ]

Crystals
[color ]

Yellow to orange
[Hydrolytic Sensitivity]

8: reacts rapidly with moisture, water, protic solvents
[Sensitive ]

Air Sensitive
[Exposure limits]

ACGIH: TWA 1 mg/m3
NIOSH: IDLH 100 mg/m3; TWA 0.1 mg/m3
[InChIKey]

WDIAJTWVVLHUJU-SUESZSCISA-N
Hazard InformationBack Directory
[Chemical Properties]

Orange crystal
[Uses]

[General Description]

Atomic number of base material: 45 Rhodium
[reaction suitability]

reagent type: catalyst
Safety DataBack Directory
[Hazard Codes ]

Xi
[Risk Statements ]

36/37/38
[Safety Statements ]

26-37/39
[WGK Germany ]

3
[RTECS ]

VI9292000
[TSCA ]

No
[HS Code ]

28439000
[Safety Profile]

Poison by intraperitoneal route. When heated to decomposition it emits toxic fumes of Rh
Questions And AnswerBack Directory
[Reactions]

  1. Precursor for asymmetric hydrogenation reactions.
  2. Rh-catalyzed carbozincation of ynamides. 
Reactions of 12245-39-5
Spectrum DetailBack Directory
[Spectrum Detail]

ACETYLACETONATO(1,5-CYCLOOCTADIENE)RHODIUM(I)(12245-39-5)MS
ACETYLACETONATO(1,5-CYCLOOCTADIENE)RHODIUM(I)(12245-39-5)1HNMR
ACETYLACETONATO(1,5-CYCLOOCTADIENE)RHODIUM(I)(12245-39-5)IR1
ACETYLACETONATO(1,5-CYCLOOCTADIENE)RHODIUM(I)(12245-39-5)IR2
ACETYLACETONATO(1,5-CYCLOOCTADIENE)RHODIUM(I)(12245-39-5)Raman
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