| Identification | Back Directory | [Name]
Bis[(pentamethylcyclopentadienyl)dichloro-rhodium] | [CAS]
12354-85-7 | [Synonyms]
Bis[(pentamethylcycl
PENTAMETHYLCYCLOPENTADIENYLRHODIUM(III)&
PENTAMETHYLCYCLOPENTADIENYLRHODIUM CHLORIDE DIMER
Bis(dichloro(pentamethylcyclopentadienyl)rhodium)
Bis(pentamethylcyclopentadienylrhodium dichloride)
BIS[(PENTAMETHYLCYCLOPENTADIENYL)DICHLORO-RHODIUM]
Tetrachlorobis(pentamethylcyclopentadienyl)dirhodium
Pentamethylcyclopentadienylrhodium(Ⅲ) chloride dimer
PentaMethyl cyclopentadienyl RhodiuM dichloride diMer
DICHLOROPENTAMETHYLCYCLOPENTADIENYLRHODIUM(III) DIMER
PENTAMETHYLCYCLOPENTADIENYLRHODIUM(III) CHLORIDE DIMER
Dichloro(pentamethylcyclopentadienyl)rhodium(II) dimer
PentaMethylcyclopentadienylrhodiuM(III) chloride diMer 97%
Dichloro(pentamethylcyclopentadienyl)rhodium(III)dimer,99%
(Pentamethylcyclopentadienyl)rhodium(III) Dichloride Dimer
Di-μ-chlorodichlorobis(pentamethylcyclopentadienyl)dirhodate
DI-M-CHLORODICHLOROBIS(PENTAMETHYLCYCLOPENTADIENYL)DIRHODATE
1,3-Cyclopentadiene, 1,2,3,4,5-pentamethyl-, rhodium complex
di-ae-chlorodichlorobis(pentamethylcyclopentadienyl)dirhodate
DI-MU-CHLORODICHLOROBIS-(PENTAMETHYLCYCLOPENTADIENYL)DIRHODATE
Di-mu-chlorodichlorobis(pentamethyl-pi-cyclopentadienyl)dirhodium
Di-mu-chlorodichlorobis-(pentamethylcyclopentadienyl)dirhodate ,98%
Dichloro(pentaMethylcyclopentadienyl)rhodiuM(III) diMer,(Cp*RhCl2)2
Dichloro(pentaMethylcyclopentadienyl)rhodiuM(III) diMer,98% (Cp*RhCl2)2
Rhodium, di-mu-chlorodichlorobis[(1,2,3,4,5-eta)-1,2,3,4,5-pentamethyl-2,4-cyclopentadien-1-yl]di-
Di-mu-chlorodichlorobis-(pentamethylcyclopentadienyl)dirhodate ,Rhodium≥31.3% Carbon≥39.0 [Rhodium≥31.3% Carbon≥39.0] | [Molecular Formula]
C20H30Cl4Rh2 10* | [MDL Number]
MFCD00061552 | [MOL File]
12354-85-7.mol | [Molecular Weight]
618.08 |
| Chemical Properties | Back Directory | [Appearance]
burgundy solid | [Melting point ]
>300°C | [storage temp. ]
Keep in dark place,Sealed in dry,Room Temperature | [solubility ]
Chloroform (Sparingly), Methanol (Slightly) | [form ]
crystal | [color ]
red | [Water Solubility ]
Soluble in chloroform and acetone. Slightly soluble in tetrahydrofuran and methanol. Insoluble in water and diethylether | [Stability:]
Hygroscopic | [InChI]
InChI=1S/2C10H15.4ClH.2Rh/c2*1-6-7(2)9(4)10(5)8(6)3;;;;;;/h2*1-5H3;4*1H;;/q;;;;;;2*+2/p-4 | [InChIKey]
QNIVKTTWBMFSBR-UHFFFAOYSA-J | [SMILES]
[C]1(C)[C](C)[C](C)[C](C)[C]1C.[C]1(C)[C](C)[C](C)[C](C)[C]1C.[Rh](Cl)Cl.[Rh](Cl)Cl |^1:0,2,4,6,8,10,12,14,16,18| | [NIST Chemistry Reference]
Rhodium, di-«mu»-chlorodichlorobis[(1,2,3,4,5-«eta»)-1,2,3,4,5-pentamethyl-2,4-cyclopentadien-1-yl]di-(12354-85-7) |
| Hazard Information | Back Directory | [Chemical Properties]
burgundy solid | [Uses]
Oxidative olefination reactions C-C bond cleavage of secondary alcohols Ortho C-H olefination of phenol derivatives Oxidative annulation of pyridines Oxidative ortho-acylation of benzamides with aldehydes via direct functionalization of the sp2 C-H bond A | [reaction suitability]
core: rhodium
reaction type: Cross Couplings
reagent type: catalyst
reaction type: C-H Activation |
| Questions And Answer | Back Directory | [Reaction]
- Catalyst used in the functionalization of acetanilides under solventless conditions in a ball mill.
- Rhodiumcatalyzed regioselective direct C-H arylation of indoles with aryl boronic acids.
- Catalyst used in the asymmetric transfer hydrogenation of imines in water.
- Facile rhodium-catalyzed synthesis of fluorinated pyridines.
- Rhodium-catalyzed alkylation of azobenzenes with allyl acetates.
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