| Identification | Back Directory | [Name]
N-[2-(di-1-adamantylphosphino) phenyl]morpholine,98% Mor-DalPhos | [CAS]
1237588-12-3 | [Synonyms]
Mor-DalPhos
MorDalphos 97%
98% Mor-DalPhos
Di(1-adamantyl)-2-morpholinophenylphosphine
Bis(adamant-1-yl)(2-morpholinophenyl)phosphine
N-[2-(di-1-adaMantylphosphino)phenyl]Morpholine
4-(2-(Di(adamantan-1-yl)phosphino)phenyl)morpholine
4-(2-(di(adamantan-1-yl)phosphanyl)phenyl)morpholine
N-[2-(di-1-adaMantylphosphino)phenyl]Morpholine Mor-DalPhos
Bis(1-adamantyl)(2-morpholinophenyl)-phosphine (Mor-DalPhos)
N-[2-(di-1-adamantylphosphino) phenyl]morpholine,98% Mor-DalPhos | [Molecular Formula]
C30H42NOP | [MDL Number]
MFCD17018759 | [MOL File]
1237588-12-3.mol | [Molecular Weight]
463.634 |
| Chemical Properties | Back Directory | [Melting point ]
219-224°C | [storage temp. ]
2-8°C | [form ]
crystal | [pka]
4.75±0.40(Predicted) | [color ]
white to yellow | [Sensitive ]
air sensitive | [InChI]
InChI=1S/C30H42NOP/c1-2-4-28(27(3-1)31-5-7-32-8-6-31)33(29-15-21-9-22(16-29)11-23(10-21)17-29)30-18-24-12-25(19-30)14-26(13-24)20-30/h1-4,21-26H,5-20H2 | [InChIKey]
CCBRRSUORFMQCZ-UHFFFAOYSA-N | [SMILES]
N1(C2=CC=CC=C2P(C23CC4CC(CC(C4)C2)C3)C23CC4CC(CC(C4)C2)C3)CCOCC1 | [CAS DataBase Reference]
1237588-12-3 |
| Questions And Answer | Back Directory | [Reaction]
- P-N-ligand for use in the Pd-catalyzed cross-coupling of ammonia and hydrazine. Ref. (2) with a diverse range of sterically hindered, unbiased aryl chlorides. Low catalyst loading and mild conditions. Ref (5) with diamines in a chemoselective arylation process. Ref (6) with solvent-free or aqueous conditions.
- P-N-ligand for the gold-catalyzed stereoselective hydroamination of internal alkynes with dialkylamines to afford E-amines.
- P-N-ligand for use in the Pd-catalyzed for mono-α-arylation of ketones employing aryl chlorides, bromides, iodides, mesylates (Ref. 7) and tosylates.
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| Hazard Information | Back Directory | [Uses]
Mor-DalPhos is a versatile and efficient green catalytic system for Buchwald-Hartwig cross-coupling reaction of aryl bromides or chlorides with a large set amines, amides, ureas, and carbamates. | [reaction suitability]
reagent type: ligand
reaction type: Arylations
reagent type: ligand
reaction type: Buchwald-Hartwig Cross Coupling Reaction |
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