ChemicalBook--->CAS DataBase List--->125486-96-6

125486-96-6

125486-96-6 Structure

125486-96-6 Structure
IdentificationBack Directory
[Name]

2-(TRIMETHYLSILYL)ETHANESULFONAMIDE, 90%
[CAS]

125486-96-6
[Synonyms]

SES-NH2
2-Trimethylsilylethanesulfonyl amide
beta-(Trimethylsilyl)ethanesulfonamide
Ethanesulfonamide, 2-(trimethylsilyl)-
2-(trimethylsilyl)ethane-1-sulfonamide
2-(Trimethylsilyl)ethanesulfonamide 90%
2-(TRIMETHYLSILYL)ETHANESULFONAMIDE, 90%
2-(TRIMETHYLSILYL)ETHANESULFONAMIDE, 90% ISO 9001:2015 REACH
[Molecular Formula]

C5H15NO2SSi
[MDL Number]

MFCD09265152
[MOL File]

125486-96-6.mol
[Molecular Weight]

181.329
Chemical PropertiesBack Directory
[Melting point ]

81-87 °C
[Boiling point ]

253.0±42.0 °C(Predicted)
[density ]

1.057±0.06 g/cm3(Predicted)
[storage temp. ]

Store at 0-8 °C
[solubility ]

Soluble in benzene, chloroform, dichloromethane, ether, methanol and toluene.
[form ]

solid
[pka]

10.99±0.60(Predicted)
[Appearance]

yellow solid
[InChI]

1S/C5H15NO2SSi/c1-10(2,3)5-4-9(6,7)8/h4-5H2,1-3H3,(H2,6,7,8)
[InChIKey]

MZASHBBAFBWNFL-UHFFFAOYSA-N
[SMILES]

C[Si](C)(C)CCS(N)(=O)=O
Hazard InformationBack Directory
[Uses]

Useful reagent for introduction of a SES-protected nitrogen functionality, which can be cleaved with fluoride ion.1
[Preparation]

2-(Trimethylsilyl)ethanesulfonamide is prepared by reaction of 2-(trimethylsilyl) ethanesulfonyl chloride (accessible from the commercially available sodium salt of the corresponding sulfonic acid or starting from vinyl trimethylsilane) with gaseous ammonia (eq 1).

125486-96-6 synthesis

Safety DataBack Directory
[Symbol(GHS) ]


GHS07
[Signal word ]

Warning
[Hazard statements ]

H315-H319-H335
[Precautionary statements ]

P261-P264-P271-P280-P302+P352-P305+P351+P338
[Hazard Codes ]

Xi
[Risk Statements ]

36/37/38
[Safety Statements ]

26
[RIDADR ]

UN 3335
[WGK Germany ]

3
[Storage Class]

11 - Combustible Solids
[Hazard Classifications]

Eye Irrit. 2
Skin Irrit. 2
STOT SE 3
Spectrum DetailBack Directory
[Spectrum Detail]

2-(TRIMETHYLSILYL)ETHANESULFONAMIDE, 90%(125486-96-6)1HNMR
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