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1258327-07-9

1258327-07-9 Structure

1258327-07-9 Structure
IdentificationBack Directory
[Name]

(11aS)-3,7-Bis[3,5-bis(trifluoromethyl)phenyl]-10,11,12,13-tetrahydro-5-hydroxy-diindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin 5-oxide
[CAS]

1258327-07-9
[Synonyms]

(11aS)-3,7-Bis[3,5-bis(trifluoromethyl)phenyl]-10,11,12,13-tetrahydro-5-hydroxy-diindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin 5-oxide
(11aS)-5-oxide-3,7-bis[3,5-bis(trifluoroMethyl)phenyl]-10,11,12,13-tetrahydro-5-hydroxy-Diindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin
(11aS)-3,7-Bis[3,5-bis(trifluoromethyl)phenyl]-10,11,12, 13-tetrahydro-5-hydroxy-5-oxide-diindeno[7,1-de:1',7'-fg] [1,3,2]dioxaphosphocin
(11aS)-3,7-Bis[3,5-bis(trifluoromethyl)phenyl]-10,11,12,13-tetrahydro-5-hydroxy-5-oxide-diindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin,99%e.e.
(11aS)-3,7-Bis[3,5-bis(trifluoromethyl)phenyl]-10,11,12,13-tetrahydro-5-hydroxy-5-oxide-diindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin, min. 98%
[Molecular Formula]

C33H20F12O4P
[MOL File]

1258327-07-9.mol
[Molecular Weight]

739.464
Chemical PropertiesBack Directory
[Melting point ]

>300℃
[density ]

1.64±0.1 g/cm3 (20 ºC 760 Torr)
[form ]

Powder
[color ]

white to light-yellow
Questions And AnswerBack Directory
[Reaction]

  1. Organocatalytic asymmetric multicomponent reactions of aromatic aldehydes and anilines with β-ketoesters: facile and atomeconomical access to chiral tetrahydropyridines.
  2. Pd(0)-catalyzed tandem deprotection/cyclization of tetrahydro-β-carbolines on allenes: application to the synthesis of indolo[2,3-α]quinolizidines.
  3. Enantioselective synthesis of benzazepinoindoles bearing trifluoromethylated quaternary stereocenters, catalyzed by chiral spirocyclic phosphoric acids.
Reactions of 1258327-07-9
Spectrum DetailBack Directory
[Spectrum Detail]

(11aS)-3,7-Bis[3,5-bis(trifluoromethyl)phenyl]-10,11,12,13-tetrahydro-5-hydroxy-diindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin 5-oxide(1258327-07-9)1HNMR
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