| Identification | Back Directory | [Name]
Garg 4,5-indolyne precusor 95% | [CAS]
1259448-37-7 | [Synonyms]
Garg 4,5-indolyne precusor
Garg 4,5-indolyne precursor
Garg 4,5-indolyne precusor 95%
Methanesulfonic acid, 1,1,1-trifluoro-, 4-(trimethylsilyl)-1H-indol-5-yl ester | [Molecular Formula]
C12H14F3NO3SSi | [MDL Number]
MFCD25976536 | [MOL File]
1259448-37-7.mol | [Molecular Weight]
337.39 |
| Chemical Properties | Back Directory | [Melting point ]
43-48°C | [Fp ]
>110℃ | [storage temp. ]
2-8°C | [form ]
solid | [InChI]
1S/C12H14F3NO3SSi/c1-21(2,3)11-8-6-7-16-9(8)4-5-10(11)19-20(17,18)12(13,14)15/h4-7,16H,1-3H3 | [InChIKey]
LLCJFYYASDIOJN-UHFFFAOYSA-N | [SMILES]
O=S(OC1=C([Si](C)(C)C)C2=C(NC=C2)C=C1)(C(F)(F)F)=O |
| Safety Data | Back Directory | [WGK Germany ]
3 | [Storage Class]
11 - Combustible Solids | [Hazard Classifications]
Eye Irrit. 2
Skin Irrit. 2
STOT SE 3 |
| Hazard Information | Back Directory | [Uses]
Indolyne precursor can be activated under mild fluoride conditions, which are highly reactive with dienes and other dipolariphiles (e.g. azides) to provide cycloaddition products containing an indole motif. | [General Description]
Garg 4,5-indolyne precursor is an indolyne precursor developed by Professor Neil Garg and coworkers. It is widely used for the synthesis of various N-heterocyclic based compounds. It is also useful for the preparation of substituted indoles (Diels–Alder and azide cycloaddition products). |
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Sigma-Aldrich
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Energy Chemical
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http://www.energy-chemical.com |
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Merck KGaA
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www.sigmaaldrich.cn |
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