| Identification | Back Directory | [Name]
lasiocarpine N-oxide | [CAS]
127-30-0 | [Synonyms]
Lasiocarpin-N-oxid
lasiocarpine N-oxide
Lasiocarpine N-oxide-RM
4-21-00-02054 (Beilstein Handbook Reference)
7-[(E)-2-methylbut-2-enoyl]oxy-4-oxido-5,6,7,8-tetrahydro-3H-pyrrolizin-4-ium-1-yl]methyl 2,3-dihydroxy-2-(1-methoxyethyl)-3-methylbutanoate
(1S)-1β-[(Z)-2-Methyl-2-butenoyloxy]-2,3,5,7aβ-tetrahydro-7-[[[(2R)-2,3-dihydroxy-2-[(S)-1-methoxyethyl]-3-methylbutanoyl]oxy]methyl]-1H-pyrrolizine 4-oxide
(7aR)-7-[(Ξ)-2,3-dihydroxy-2-((Ξ)-1-methoxy-ethyl)-3-methyl-butyryloxymethyl]-1c-(2-methyl-cis-crotonoyloxy)-(4ξ,7ar)-2,3,5,7a-tetrahydro-1H-pyrrolizin-4-oxide
2-Butenoic acid, 2-methyl-, (1S,7aR)-7-[[(2R)-2,3-dihydroxy-2-[(1R)-1-methoxyethyl]-3-methyl-1-oxobutoxy]methyl]-2,3,5,7a-tetrahydro-4-oxido-1H-pyrrolizin-1-yl ester, (2Z)- | [Molecular Formula]
C21H33NO8 | [MDL Number]
MFCD01716329 | [MOL File]
127-30-0.mol | [Molecular Weight]
427.489 |
| Safety Data | Back Directory | [RIDADR ]
1544 | [HazardClass ]
6.1(b) | [PackingGroup ]
III | [Toxicity]
rat,LD50,intraperitoneal,181mg/kg (181mg/kg),GASTROINTESTINAL: "HYPERMOTILITY, DIARRHEA"KIDNEY, URETER, AND BLADDER: HEMATURIAGASTROINTESTINAL: OTHER CHANGES,Journal of Pathology and Bacteriology. Vol. 75, Pg. 17, 1958. |
| Hazard Information | Back Directory | [Description]
The seeds of Heliotropium europeum have been shown to contain this alkaloid.
Reduction with Zn and dilute H2S04 furnishes Lasiocarpine (q.v.). | [Uses]
Lasiocarpine N-Oxide is a natural compound found to be higher in varied tea bags, herbal drugs and honey by mass spectrometry. | [References]
Culvenor, Drummond, Price., Austral. J. Chem., 7, 277 (1954)
Culvenor., ibid, 7,287 (1954) |
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