| Identification | Back Directory | [Name]
(R)-N-((3-Methylpyridin-2-yl)methyl)-7′-di(3,5-di-tert-butylphenyl)phosphino-1,1′-spirobiindanyl-7-amine | [CAS]
1298133-36-4 | [Synonyms]
(R)-SpiroPAP-Me
(R)-DTB-SpiroPAP-3-Me
(R)-N-((3-Methylpyridin-2-yl)methyl)-7′-di(3,5-di-tert-butylphenyl)phosphino-1,1′-spirobiindanyl-7-amine
N-[(1R)-7'-[Bis[3,5-bis(tert-butyl)phenyl]phosphino]-2,2',3,3'-tetrahydro-1,1'-spirobi[1H-inden]-7-yl]-3-methyl-2-pyridinemethanamine,99%e.e. | [Molecular Formula]
C52H65N2P | [MDL Number]
MFCD30187941 | [MOL File]
1298133-36-4.mol | [Molecular Weight]
749.06 |
| Chemical Properties | Back Directory | [Melting point ]
160-161°C | [alpha ]
+213 (c 0.5, CH2Cl2) | [Boiling point ]
764.0±60.0 °C(Predicted) | [storage temp. ]
2-8°C, protect from light, stored under nitrogen | [form ]
solid | [pka]
5.04±0.22(Predicted) | [color ]
off-white | [Sensitive ]
air sensitive |
| Questions And Answer | Back Directory | [Reactions]
- Iridium/ligand catalyst for the highly efficient, asymmetric hydrogenation of β-aryl and β-ketoesters.
- Extremely efficient chiral iridium catalyst used for the asymmetric hydrogenation of ketones.
- Iridium/ligand catalyst for the highly efficient, asymmetric hydrogenation of β-aryl and β-ketoesters.
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