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129986-67-0

129986-67-0 Structure

129986-67-0 Structure
IdentificationBack Directory
[Name]

N-METHOXY-N-METHYL(TRIPHENYL-PHOSPHORANYLIDENE)ACETAMIDE
[CAS]

129986-67-0
[Synonyms]

N-METHOXY-N-METHYL(TRIPHENYL-PHOSPHORANYLIDENE)ACETAMIDE
N-METHOXY-N-METHYL-2-(TRIPHENYLPHOSPHORANYLIDENE)ACETAMIDE
(N-methoxymethylaminocarbonylmethylene)triphenylphosphoran
N-Methoxy-N-methyl(triphenylphosphoranylidene)acetamide 98%
N-methoxy-N-methyl-2-(triphenyl-l5-phosphanylidene)acetamide
[N-METHOXYMETHYLAMINOCARBONYLMETHYLENE]-TRIPHENYLPHOSPHORANE
N-Methoxy-N-methyl-2-(triphenylphosphoranylidene)acetamide, 98 %
[Molecular Formula]

C22H22NO2P
[MDL Number]

MFCD00144930
[MOL File]

129986-67-0.mol
[Molecular Weight]

363.39
Chemical PropertiesBack Directory
[Appearance]

White to off-white powder
[Melting point ]

183 °C
[Boiling point ]

495.6±28.0 °C(Predicted)
[density ]

1.18±0.1 g/cm3(Predicted)
[storage temp. ]

-20°C Freezer, Under inert atmosphere
[solubility ]

Chloroform (Slightly), Methanol (Slightly)
[form ]

Solid
[color ]

Off White to Pale Yellow
[BRN ]

4198472
[InChI]

1S/C22H22NO2P/c1-23(25-2)22(24)18-26(19-12-6-3-7-13-19,20-14-8-4-9-15-20)21-16-10-5-11-17-21/h3-18H,1-2H3
[InChIKey]

DGBLSOOPDBHHRX-UHFFFAOYSA-N
[SMILES]

CON(C)C(=O)C=P(c1ccccc1)(c2ccccc2)c3ccccc3
Hazard InformationBack Directory
[Chemical Properties]

White to off-white powder
[Uses]

Reactant for:
  • Synthesis of electron-deficient alkenes via stereoselective olefination of N-sulfonyl imines
  • Phosphine-catalyzed asymmetric addition reactions
  • Cysteine-catalyzed enantioselective intramolecular Rauhut-Currier reaction
  • Wittig olefination
  • Synthesis of aigialomycin D, a Protein Kinase inhibitor and a potential anticancer agent
[reaction suitability]

reaction type: C-C Bond Formation
Safety DataBack Directory
[Symbol(GHS) ]

Exclamation Mark (GHS07)
GHS07
[Signal word ]

Warning
[Hazard statements ]

H315-H319-H335
[Precautionary statements ]

P261-P264-P271-P280-P302+P352-P305+P351+P338
[Hazard Codes ]

Xi
[Risk Statements ]

36/37/38
[Safety Statements ]

26-36
[WGK Germany ]

3
[F ]

9
[HS Code ]

29241900
[Storage Class]

11 - Combustible Solids
[Hazard Classifications]

Eye Irrit. 2
Skin Irrit. 2
STOT SE 3
Spectrum DetailBack Directory
[Spectrum Detail]

N-METHOXY-N-METHYL(TRIPHENYL-PHOSPHORANYLIDENE)ACETAMIDE(129986-67-0)1HNMR
N-METHOXY-N-METHYL(TRIPHENYL-PHOSPHORANYLIDENE)ACETAMIDE(129986-67-0)Raman
N-METHOXY-N-METHYL(TRIPHENYL-PHOSPHORANYLIDENE)ACETAMIDE(129986-67-0)IR
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