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130296-28-5

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130296-28-5 Structure

130296-28-5 Structure
IdentificationBack Directory
[Name]

Bis(1,5-cyclooctadiene)rhodium(I) hexafluoroantimonate
[CAS]

130296-28-5
[Synonyms]

Bis(1,5-cyclooctadiene)rhodium(I) hexafluoroantimonate
Bis(1,5-cycloocatadiene)rhodium(I) hexafluoroantimonate
[Molecular Formula]

C16H24F6RhSb
[MDL Number]

MFCD11113031
[MOL File]

130296-28-5.mol
Chemical PropertiesBack Directory
[Appearance]

brown crystal
[Melting point ]

58-60 °C
[storage temp. ]

?20°C
[form ]

Crystalline powder
[Sensitive ]

Air stable, moisture sensitive
[InChI]

1S/2C8H12.6FH.Rh.Sb/c2*1-2-4-6-8-7-5-3-1;;;;;;;;/h2*1-2,7-8H,3-6H2;6*1H;;/q;;;;;;;;+1;+5/p-6/b2*2-1-,8-7-;;;;;;;;
[InChIKey]

BROZUPPJWNODCU-SXGOCSEPSA-H
[SMILES]

[Rh+].F[Sb-](F)(F)(F)(F)F.C1CC=CCCC=C1.C2CC=CCCC=C2
Hazard InformationBack Directory
[Chemical Properties]

brown crystal
[Uses]

Catalyst for:
  • [3+2] Cycloaddition
  • Preparation of diastereomeric chiral phosphorus mon- and bidentate diamidophosphite ligands based on dianydromannitol and their use in asymmetric metallocomplex catalysis
  • C-C bond-forming hydrogenation
[reaction suitability]

core: rhodium
reagent type: catalyst
Safety DataBack Directory
[Symbol(GHS) ]

GHS hazard pictogramsGHS hazard pictograms
GHS07,GHS09
[Signal word ]

Warning
[Hazard statements ]

H302+H332-H411
[Precautionary statements ]

P261-P264-P270-P273-P301+P312-P304+P340+P312
[WGK Germany ]

3
[HazardClass ]

9
[Storage Class]

11 - Combustible Solids
[Hazard Classifications]

Acute Tox. 4 Inhalation
Acute Tox. 4 Oral
Aquatic Chronic 2
Spectrum DetailBack Directory
[Spectrum Detail]

Bis(1,5-cyclooctadiene)rhodium(I) hexafluoroantimonate(130296-28-5)1HNMR
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