ChemicalBook--->CAS DataBase List--->13036-81-2

13036-81-2

13036-81-2 Structure

13036-81-2 Structure
IdentificationBack Directory
[Name]

1,3,5-TRI-N-PROPYL HEXAHYDRO-S-TRIAZINE
[CAS]

13036-81-2
[Synonyms]

Ai3-51515
Einecs 235-904-6
1,3,5-Tripropyl-1,3,5-triazinane
Hexahydro-1,3,5-tripropyl-s-triazine
1,3,5-TRI-N-PROPYL HEXAHYDRO-S-TRIAZINE
hexahydro-1,3,5-tripropyl-1,3,5-triazine
1,3,5-Triazine, hexahydro-1,3,5-tripropyl-
1,3,5-Tri-n-propylhexahydro-1,3,5-triazine
1,3,5-Tri-n-propylhexahydro-1,3,5-triazine,96%
[EINECS(EC#)]

235-904-6
[Molecular Formula]

C12H27N3
[MDL Number]

MFCD00040461
[MOL File]

13036-81-2.mol
[Molecular Weight]

213.36
Chemical PropertiesBack Directory
[Boiling point ]

94℃/0.7mm
[density ]

0.880
[refractive index ]

1.4660
[storage temp. ]

Sealed in dry,Room Temperature
[form ]

Liquid
[pka]

6.72±0.20(Predicted)
[color ]

Colorless
[EPA Substance Registry System]

1,3,5-Triazine, hexahydro-1,3,5-tripropyl- (13036-81-2)
Safety DataBack Directory
[Symbol(GHS) ]

Exclamation Mark (GHS07)
GHS07
[Signal word ]

Warning
[Hazard statements ]

H302-H312-H315-H319
[Precautionary statements ]

P280-P301+P312a-P305+P351+P338-P321-P332+P313-P501a
[TSCA ]

Yes
Hazard InformationBack Directory
[Synthesis]

Propylamine

107-10-8

Formaldehyde

50-00-0

1,3,5-TRI-N-PROPYL HEXAHYDRO-S-TRIAZINE

13036-81-2

To a stirred suspension of anhydrous MgSO4 in dichloromethane (25 mL) was sequentially added paraformaldehyde (0.56 g, 18.7 mmol) and freshly distilled n-propylamine (18.7 mmol). The reaction mixture was stirred at room temperature. Upon completion of the reaction, the MgSO4 was removed by filtration and the filtrate was concentrated in vacuum to afford the crude product of 1,3,5-tripropyl-1,3,5-triazacyclohexane, which could be used in the subsequent steps without further purification.

[References]

[1] Synthesis (Germany), 2018, vol. 50, # 10, p. 2001 - 2008
[2] Journal of the Chemical Society, 1931, p. 1490,1492
[3] Journal of Pharmaceutical Sciences, 1990, vol. 79, # 1, p. 66 - 73
[4] Journal of Polymer Science, Part A: Polymer Chemistry, 2010, vol. 48, # 13, p. 2777 - 2782
[5] Bl.Acad.Belg., vol. <3>26, p. 203;29,30
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