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130914-24-8

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130914-24-8 Structure

130914-24-8 Structure
IdentificationBack Directory
[Name]

CHLORODICYCLOPENTYLPHOSPHINE 97
[CAS]

130914-24-8
[Synonyms]

CHLORODICYCLOPENTYLPHOSPHIN
Dicyclopentylchlorophosphine
Dicyclopentylphosphine chloride
CHLORODICYCLOPENTYLPHOSPHINE 97
Phosphinous chloride, P,P-dicyclopentyl-
[Molecular Formula]

C10H18ClP
[MDL Number]

MFCD06798131
[MOL File]

130914-24-8.mol
[Molecular Weight]

204.68
Chemical PropertiesBack Directory
[Boiling point ]

258.2±7.0 °C(Predicted)
[density ]

1.069 g/mL at 25 °C(lit.)
[Fp ]

>230 °F
Safety DataBack Directory
[Hazard Codes ]

C
[Risk Statements ]

14-34
[Safety Statements ]

26-36/37/39-45
[RIDADR ]

UN 3265 8/PG 2
[WGK Germany ]

3
Hazard InformationBack Directory
[Uses]

Chlorodicyclopentylphosphine may be used to prepare:
  • Cp,Cp-MannOP, a chiral diphosphinite ligand by reacting with mannitol.[Cp=cyclopentyl; Mann=mannitol]
  • (S)-Cp,Cp-oxoProNOP, a bis(dicycloalkylphosphino) amidophosphine-phosphinite ligand by reacting with (S)-5-(hydroxymethyl)-2-pyrrolidinone
  • LcPeNiCl, a precursor for preparing LcPeNiH, which is an efficient catalyst for the reduction of CO2[cPe=cyclopentyl]
[General Description]

Chlorodicyclopentylphosphine is a phosphine precursor for ligand preparation in Negishi and Suzuki coupling reactions.
[reaction suitability]

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
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