| Identification | Back Directory | [Name]
(R,R)-2,2'-(2,6-PYRIDINEDIYL)BIS(4-ISOPROPYL-2-OXAZOLINE) | [CAS]
131864-67-0 | [Synonyms]
2,6-bis((4R)-(+)-isopropyl-2-oxazolin-2-yl)pyridi
(R,R)-2,6-BIS(4-ISOPROPYL-2-OXAZOLIN-2-YL)PYRIDINE
2,6-BIS[(4R)-(+)-ISOPROPYL-2-OXAZOLIN-2-YL]PYRIDINE
(+)-2,6-BIS[(4R)-4-(I-PROPYL)-2-OXAZOLIN-2-YL]PYRIDINE
2,6-bis((R)-4-isopropyl-4,5-dihydrooxazol-2-yl)pyridine
2,6-Bis[(4R)-(+)-isopropyl-2-oxazolin-2-yl]pyridine 99%
2,6-Bis[(4R)-isopropyl-2-oxazolin-2-yl]pyridine,99%e.e.
(R,R)-2,2'-(2,6-PYRIDINEDIYL)BIS(4-ISOPROPYL-2-OXAZOLINE)
(+)-2,6-Bis[(4R)-4-(i-propyl)-2-oxazolin-2-yl]pyridine,97%
(+)-2,6-Bis[(4R)-4-(i-propyl)-2-oxazolin-2-yl]pyridine,98+%
(+)-2,6-Bis[(4R)-4-(i-propyl)-2-oxazolin-2-yl]pyridine, 98+% (R)-(i-Pr)-pybox | [Molecular Formula]
C17H23N3O2 | [MDL Number]
MFCD01321334 | [MOL File]
131864-67-0.mol | [Molecular Weight]
301.38 |
| Chemical Properties | Back Directory | [Melting point ]
154-156 °C(lit.)
| [alpha ]
+118° (c 1.0, CH2Cl2) | [Boiling point ]
457.1±30.0 °C(Predicted) | [density ]
1.23±0.1 g/cm3(Predicted) | [refractive index ]
118 ° (C=1, CH2Cl2) | [storage temp. ]
Refrigerator | [form ]
crystal | [pka]
3.78±0.70(Predicted) | [color ]
white | [Optical Rotation]
[α]20/D +118°, c = 0.7 in methylene chloride | [InChI]
InChI=1S/C17H23N3O2/c1-10(2)14-8-21-16(19-14)12-6-5-7-13(18-12)17-20-15(9-22-17)11(3)4/h5-7,10-11,14-15H,8-9H2,1-4H3/t14-,15-/m0/s1 | [InChIKey]
CSGQGLBCAHGJDR-GJZGRUSLSA-N | [SMILES]
C1(C2=N[C@H](C(C)C)CO2)=NC(C2=N[C@H](C(C)C)CO2)=CC=C1 |
| Hazard Information | Back Directory | [Chemical Properties]
White powder | [Uses]
C2 symmetric ligand for enantioselective catalysis. Easily forms bidentate coordination complexes due to the strong affinity of the oxazoline nitrogen for various metals. |
| Safety Data | Back Directory | [Hazard Codes ]
Xi | [Risk Statements ]
36/37/38 | [Safety Statements ]
26-36 | [WGK Germany ]
3
| [HazardClass ]
IRRITANT | [HS Code ]
29349990 | [Storage Class]
11 - Combustible Solids | [Hazard Classifications]
Eye Irrit. 2
Skin Irrit. 2
STOT SE 3 |
| Questions And Answer | Back Directory | [Reaction]
- Ligand for enantioselective nitrone cycloaddition to α,β-unsaturated 2-acyl imidazoles.
- Highly efficient catalytic enantioselective Mannich reaction of malonates with N-tert-butoxycarbonyl imines.
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