| Identification | Back Directory | [Name]
Bis[(2-di-i-propylphosphino]ethyl)amine, min. 97% | [CAS]
131890-26-1 | [Synonyms]
Bis[(2-di-i-propylphosphino]ethyl)aMine
Bis((2-diisopropylphosphino)ethyl)-amine
Bis[(2-diisopropylphosphino]ethyl)amine solution
Bis[(2-di-i-propylphosphino]ethyl)amine, min. 97%
Bis[2-(diisopropylphosphino)ethyl]aMine, 10% w/w soln. in THF
Bis[(2-di-i-propylphosphino)ethyl]amine(10 wt% in tetrahydrofuran)
Bis[(2-di-i-propylphosphino)ethyl]aMine, Min. 97% (10 wt% in tetrahydrofuran) | [Molecular Formula]
C16H37NP2 | [MDL Number]
MFCD17018778 | [MOL File]
131890-26-1.mol | [Molecular Weight]
305.419 |
| Chemical Properties | Back Directory | [Boiling point ]
375.9±27.0 °C(Predicted) | [density ]
0.884 g/mL at 25 °C | [Fp ]
-17 °C | [refractive index ]
1.4180 | [form ]
liquid | [pka]
10.42±0.19(Predicted) | [color ]
pale yellow to colorless | [Water Solubility ]
Immiscible with water. | [Sensitive ]
Air Sensitive | [Exposure limits]
ACGIH: TWA 50 ppm; STEL 100 ppm (Skin)
OSHA: TWA 200 ppm(590 mg/m3)
NIOSH: IDLH 2000 ppm; TWA 200 ppm(590 mg/m3); STEL 250 ppm(735 mg/m3) | [InChI]
1S/C16H37NP2/c1-13(2)18(14(3)4)11-9-17-10-12-19(15(5)6)16(7)8/h13-17H,9-12H2,1-8H3 | [InChIKey]
FTVIGQGOGIHMBS-UHFFFAOYSA-N | [SMILES]
CC(C)P(CCNCCP(C(C)C)C(C)C)C(C)C |
| Safety Data | Back Directory | [Hazard Codes ]
F,Xn | [Risk Statements ]
11-19-36/37-40 | [Safety Statements ]
16-26-36/37 | [RIDADR ]
UN 2056 3 / PGII | [WGK Germany ]
3 | [HS Code ]
2931.39.0030 | [HazardClass ]
3 | [Storage Class]
3 - Flammable liquids | [Hazard Classifications]
Acute Tox. 4 Oral
Carc. 2
Eye Irrit. 2
Flam. Liq. 2
Skin Irrit. 2
STOT SE 3 |
| Questions And Answer | Back Directory | [Reaction]
- Ligand for the osmium dehydrogenation of alcohols
- Ligand for the ruthenium dehydrogenation of alcohols
- Ligand for the iron catalyzed production of hydrogen from methanol
- Ligand for the iron catalyzed hydrogenation of esters to alcohols
|
| Hazard Information | Back Directory | [Uses]
Bis[2-(diisopropylphosphino)ethyl]amine acts as ligand and form complexes with ruthenium, which finds application in the dehydrogenation of ethanol. |
|
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Sigma-Aldrich
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