ChemicalBook--->CAS DataBase List--->131929-63-0

131929-63-0

131929-63-0 Structure

131929-63-0 Structure
IdentificationBack Directory
[Name]

Spinosad D
[CAS]

131929-63-0
[Synonyms]

DE 105
Tracer
Xde-105
Spintor
Success
Spinoace
Spinosyn
Conserve
A 83543D
Naturalyte
Spinosad D
spinosyn D
Unii-78G4631rtt
Spinosad factor d
Lepicidin D, A 83543D
Spinosad D Solution in Methanol,100μg/mL
1H-as-Indaceno3,2-doxacyclododecin-7,15-dione, 2-(6-deoxy-2,...
1H-As-indaceno(3,2-D)oxacyclododecin-7,15-dione, 2-((6-deoxy-2,3,4-tri-o-methyl-alpha-L-mannopyranosyl)oxy)-13-(((2R,5S,6R)-5-(dimethylamino)tetrahydro-6-methyl-2H-pyran-2-yl)oxy)-9-ethyl-2,3,3A,5A,5B,6,9,10,11,12,13,14,16A,16B-tetradecahydro-4,14-dimet
1H-as-Indaceno3,2-doxacyclododecin-7,15-dione, 2-(6-deoxy-2,3,4-tri-O-methyl-.alpha.-L-mannopyranosyl)oxy-13-(2R,5S,6R)-5-(dimethylamino)tetrahydro-6-methyl-2H-pyran-2-yloxy-9-ethyl-2,3,3a,5a,5b,6,9,10,11,12,13,14,16a,16b-tetradecahydro-4,14-dimethyl-, (2
1H-as-Indaceno[3,2-d]oxacyclododecin-7,15-dione,2-[(6-deoxy-2,3,4-tri-O-methyl-a-L-mannopyranosyl)oxy]-13-[[(2R,5S,6R)-5-(dimethylamino)tetrahydro-6-methyl-2H-pyran-2-yl]oxy]-9-ethyl-2,3,3a,5a,5b,6,9,10,11,12,13,14,16a,16b-tetradecahydro-4,14-dimethyl-,(2
1H-as-Indaceno[3,2-d]oxacyclododecin-7,15-dione, 2-[(6-deoxy-2,3,4-tri-O-methyl-α-L-mannopyranosyl)oxy]-13-[[(2R,5S,6R)-5-(dimethylamino)tetrahydro-6-methyl-2H-pyran-2-yl]oxy]-9-ethyl-2,3,3a,5a,5b,6,9,10,11,12,13,14,16a,16b-tetradecahydro-4,14-dimethyl-, (2S,3aR,5aS,5bS,9S,13S,14R,16aS,16bS)-
(2S,3aR,5aS,5bS,9S,13S,14R,16aS,16bS)-2-[(6-Deoxy-2,3,4-tri-O-methyl-alpha-L-mannopyranosyl)oxy]-13-[[(2R,5S,6R)-5-(dimethylamino)tetrahydro-6-methyl-2H-pyran-2-yl]oxy]-9-ethyl-2,3,3a,5a,5b,6,9,10,11,12,13,14,16a,16b-tetradecahydro-4,14-dimethyl-1H-as-indaceno[3,2-d]oxacyclododecin-7,15-dione
1H-As-indaceno(3,2-D)oxacyclododecin-7,15-dione, 2-((6-deoxy-2,3,4-tri-o- methyl-A-L-mannopyranosyl)oxy)-13-(((2R,5S,6R)-5- (dimethylamino)tetrahydro-6-methyl-2H-pyran-2-yl)oxy)-9-ethyl- 2,3,3A,5A,5B,6,9,10,11,12,13,14,16A,16B-tetradecahydro-4,14-dimethyl-, (2S,3ar,5as,5bs,9S,13S,14R,16as,16bs)-
1H-As-indaceno(3,2-D)oxacyclododecin-7,15-dione, 2-((6-deoxy-2,3,4-tri-o-methyl-alpha-L-mannopyranosyl)oxy)-13-(((2R,5S,6R)-5-(dimethylamino)tetrahydro-6-methyl-2H-pyran-2-yl)oxy)-9-ethyl-2,3,3A,5A,5B,6,9,10,11,12,13,14,16A,16B-tetradecahydro-4,14-dimethyl-, (2S,3ar,5as,5bs,9S,13S,14R,16as,16bs)-
[EINECS(EC#)]

620-162-1
[Molecular Formula]

C42H67NO10
[MDL Number]

MFCD11840659
[MOL File]

131929-63-0.mol
[Molecular Weight]

745.982
Chemical PropertiesBack Directory
[Melting point ]

169°
[alpha ]

27436 -297.5° (methanol)
[Boiling point ]

807.4±65.0 °C(Predicted)
[density ]

1.15±0.1 g/cm3(Predicted)
[storage temp. ]

Store at -20°C
[solubility ]

DMF: Soluble; DMSO: Soluble; Ethanol: Soluble; Methanol: Soluble
[form ]

A solid
[pka]

7.8(at 25℃)
[color ]

White to off-white
[InChIKey]

RDECBWLKMPEKPM-UAOLJFDJNA-N
[EPA Substance Registry System]

Spinosyn D (131929-63-0)
Raw materials And Preparation ProductsBack Directory
Hazard InformationBack Directory
[Chemical Properties]

pale off-white crystalline solid with a slight stale earthy odor. Its vapor pressure is approximately 1.3×10-10 Pa. In aqueous solution at a pH of 7.74, it is relatively stable to metals and metal ions for 28 days. Its photodegradation half-life in soil is 9-10 days; its half-life in water is <1 day. It is relatively stable in aqueous solution within the pH range of 5-7; at pH 9, its half-life is >200 days. Spinosad is a mixture of more than ten components, the main ones being A and D. Spinosad A has a melting point of 84-99.5°C and a vapor pressure of 3.2×10-10 Pa. Its solubility in water is 290 mg/L (pH 5.0), 235 mg/L (pH 7.0), and 16 mg/L (pH 9.0). Its partition coefficients are 2.8, 4.0, and 5.2 at the corresponding pH values, respectively. Spinosad D has a melting point of 161.5-170°C, a vapor pressure of 2.1×10-10 Pa, and solubilities in water of 29 mg/L (pH=5.0), 0.332 mg/L (pH=7.0), and 0.053 mg/L (pH=90.0). The partition coefficients are 3.2, 4.5, and 5.2 at the corresponding pH values, respectively.
[Uses]

Spinosyn D is the second most abundant component (comprising up to 15%) of the spinosyn fermentation complex of macrocyclic lactones. Spinosyn D is a more hydrophobic analogue, and is a potent insecticide for crop pathogens and ectoparasite control on animals, albeit less active than spinosyn A. The spinosyns have a unique mechanism of action involving disruption of nicotinic acetylcholine receptors.
[Definition]

ChEBI: A spinosyn in which the sugar amino and hydroxy groups are globally methylated with an additional methyl substituent attached to the tetracyclic skeleton. One of the two active ingredients of spinosad.
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