| Identification | Back Directory | [Name]
Chloro(crotyl)(tri-tert-butylphosphine)palladium(II) | [CAS]
1334497-00-5 | [Synonyms]
PD-162
PdCl(crotyl)(PtBu3)
[p(tBu)3]Pd(crotyl)Cl
Chloro(crotyl)(tri-tert-butylphosphine)palladium(II)
[(1,2,3-η)-(2E)-2-Buten-1-yl]chloro[tris(1,1-dimethylethyl)phosphine]palladium | [Molecular Formula]
C16H34ClPPd | [MDL Number]
MFCD25372547 | [MOL File]
1334497-00-5.mol | [Molecular Weight]
399.288 |
| Chemical Properties | Back Directory | [storage temp. ]
under inert gas (nitrogen or Argon) at 2–8 °C | [form ]
Powder | [Water Solubility ]
It is insoluble in water. | [InChI]
InChI=1S/C12H27P.C4H7.ClH.Pd/c1-10(2,3)13(11(4,5)6)12(7,8)9;1-3-4-2;;/h1-9H3;3-4H,1H2,2H3;1H;/q;;;+1/p-1/b;4-3+;; | [InChIKey]
UOHSKCLJZDRCDS-NXZCPFRHSA-M | [SMILES]
P(C(C)(C)C)(C(C)(C)C)C(C)(C)C.[Pd](Cl)C/C=C/C |
| Hazard Information | Back Directory | [Uses]
Chloro(crotyl)(tri-tert-butylphosphine)palladium(II) is also used in C-C Coupling. | [Synthesis]
In a nitrogen-filled glove box, tri-tert-butylphosphine and allyl were added to a 10 ml dry reaction vial as catalyst, and finally dry and dewatered tetrahydrofuran was added to the reaction mixture as solvent, and the resulting reaction mixture was stirr |
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