ChemicalBook--->CAS DataBase List--->134484-36-9

134484-36-9

134484-36-9 Structure

134484-36-9 Structure
IdentificationBack Directory
[Name]

(S)-2-Diphenyphosphino-2'-methoxyl-1,1'-binaphthyl
[CAS]

134484-36-9
[Synonyms]

(S)-MOP
(S)-(-)-MOP
98% (S)-MOP
(S)-2-Diphenyphosphino-2'-methoxyl-1,1'-biphthyl
(S)-2-Diphenyphosphino-2'-methoxyl-1,1'-binaphthyl
(S)-2-(DIPHENYLPHOSPHINO)-2'-METHOXY-1,1'-BINAPHTHYL
(S)-(-)-(DIPHENYLPHOSPHINO)-2'-METHOXY-1,1'-BINAPHTHYL
(S)-(-)-2-(DIPHENYLPHOSPHINO)-2'-METHOXY-1,1'-BINAPHTHYL
(S)-(2'-Methoxy[1,1'-binaphthalen]-2-yl)diphenyl-phosphine
(S)-(-)-2-(Diphenylphosphino)-2'-Methoxy-1,1'-binaphthyl (S)-MOP
[(S)-2'-Methoxy[1,1'-binaphthalen]-2-yl]diphenylphosphine,99%e.e.
(S)-(-)-(DIPHENYLPHOSPHINO)-2''-METHOXY-1,1''-BINAPHTHYL (S)-MOP
(S)-(-)-2-(Diphenylphosphino)-2'-methoxy-1,1'-binaphthyl,99%(S)-MOP
[Molecular Formula]

C33H25OP
[MDL Number]

MFCD00269686
[MOL File]

134484-36-9.mol
[Molecular Weight]

468.52
Chemical PropertiesBack Directory
[Melting point ]

175-179°C
[alpha ]

-67° ±2° (c 1, toluene)
[Boiling point ]

584.1±38.0 °C(Predicted)
[storage temp. ]

under inert gas (nitrogen or Argon) at 2-8°C
[solubility ]

almost transparency in Toluene
[form ]

Powder
[color ]

white
[Sensitive ]

air sensitive
Safety DataBack Directory
[Symbol(GHS) ]

Exclamation Mark (GHS07)
GHS07
[Signal word ]

Warning
[Hazard statements ]

H317-H319
[Precautionary statements ]

P280-P305+P351+P338
[HS Code ]

2931.90.6000
Questions And AnswerBack Directory
[Reaction]

  1. Efficient catalyst for the enantioselective hydrosilyation of 1-alkenes to optically active 2-alcohols.
  2. Ligand for palladium-catalyzed asymmetric reduction of allylic esters.
  3. Ligand for the rhodium-catalyzed asymmetric arylation of imines with organostannanes.
  4. Ligand for the rhodium-catalyzed asymmetric addition of aryland alkenylboronic acids to Isatins.
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