| Identification | Back Directory | [Name]
WASA-YU MPAA LIGAND | [CAS]
1346641-35-7 | [Synonyms]
WASA-YU MPAA LIGAND
L-Phenylalanine, 2,6-difluoro-N-[[1-propyl-1-(trichloromethyl)butoxy]carbonyl]- | [Molecular Formula]
C18H22Cl3F2NO4 | [MOL File]
1346641-35-7.mol | [Molecular Weight]
460.73 |
| Chemical Properties | Back Directory | [density ]
1.365 g/cm3±0.06 g/cm3 | [storage temp. ]
2-8°C | [form ]
solid | [Boiling point ]
521.1°C±50.0°C | [InChI]
1S/C18H22Cl3F2NO4/c1-3-8-17(9-4-2,18(19,20)21)28-16(27)24-14(15(25)26)10-11-12(22)6-5-7-13(11)23/h5-7,14H,3-4,8-10H2,1-2H3,(H,24,27)(H,25,26)/t14-/m0/s1 | [InChIKey]
MYNBDMWXOQDYED-AWEZNQCLSA-N | [SMILES]
O=C(O)[C@@H](NC(OC(CCC)(CCC)C(Cl)(Cl)Cl)=O)CC1=C(F)C=CC=C1F |
| Hazard Information | Back Directory | [Uses]
The Wasa-Yu MPAA Ligand has been reported by Yu and coworkers to promote the enantioselective C-H activation of cyclopropanes. This transformation is carried out through the coupling of organoboron reagents using palladium-mediated catalysis. | [reaction suitability]
reaction type: C-H Activation
reagent type: catalyst
reagent type: ligand
reaction type: Peptide Synthesis |
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