| Identification | Back Directory | [Name]
IRON(III) PERCHLORATE HYDRATE | [CAS]
13537-24-1 | [Synonyms]
Fe(ClO4)3
IRON PERCHLORATE
FERRIC PERCHLORATE
iron triperchlorate
IRON(III) PERCHLORATE
Ferric perchlorate, GR
iron(3+),triperchlorate
iron perchlorate-hydrate
Perchloric acid,iron salt
Perchloric acid, iron salt
IRON(+3)PERCHLORATE HYDRATE
Perchloricacid,iron(3+)salt
perchloricacid,iron(3++)salt
FERRIC PERCHLORATE, HYDRATED
Iron(III) perchlorate hydrat
Iron(III) perchlorate,95-98%
IRON(III) PERCHLORATE HYDRATE
FERRIC PERCHLORATE, DEHYDRATED
FERRIC PERCHLORATE, NON-YELLOW
Iron Perchlorate Test Solution
IRON(III) PERCHLORATE N-HYDRATE
Iron(III) perchlorate nonahydrate
Perchloric acid, iron(3+) salt (3:1)
Trishyperchloric acid iron(III) salt
Ferric perchlorate test solution(ChP)
FERRIC PERCHLORATE, DEHYDRATED REAGENT
IRON (III) PERCHLORATE HYDRATE, YELLOW
IRON(III) PERCHLORATE HYDRATE (PURPLE)
IRON(III) PERCHLORATE HYDRATE, LOW CHLORIDE
Iron(III) perchlorate hydrate, Reagent Grade
iron(iii) perchlorate hexahydrate, reagent grade | [EINECS(EC#)]
236-908-0 | [Molecular Formula]
Cl3FeH2O13 | [MDL Number]
MFCD00149705 | [MOL File]
13537-24-1.mol | [Molecular Weight]
372.21 |
| Hazard Information | Back Directory | [Chemical Properties]
yellow crystal(s); hygroscopic [STR93] | [Preparation]
This crystallizes as the pale pink decahydrate Fe(ClO4)3.10H2O
from solutions of iron(III) chloride or hydrous iron(III) oxide in perchloric acid. Upon
standing over phosphorus pentoxide the decahydrate becomes the hexahydrate ; a 9-hydrate
crystallizes from solution above 42°. This salt has been important in the study of the
hydrated Fe3+ ion since perchlorate ions have only very low coordinating ability. | [Purification Methods]
Crystallise it twice from conc HClO4, the first time in the presence of a small amount of H2O2 to ensure that the iron is fully oxidised [Sullivan J Am Chem Soc 84 4256 1962]. Extreme care should be taken with this preparation because it is potentially EXPLOSIVE. |
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