| Identification | Back Directory | [Name]
ETHYL 4-METHYL-2-CYCLOHEXANONE-1-CARBOXYLATE | [CAS]
13537-82-1 | [Synonyms]
NSC 84213
Ai3-18159
Einecs 236-910-1
2-Carbethoxy-5-methylcyclohexanone
ethyl 4-methyl-2-oxocyclohexanecarboxylate
ETHYL 4-METHYL-2-CYCLOHEXANONE-1-CARBOXYLATE
ETHYL 4-METHYL-2-OXO-1-CYCLOHEXANECARBOXYLATE
ethyl4-?methyl-?2-?oxocyclohexane-?1-?carboxylate
2-Oxo-4-methylcyclohexanecarboxylic acid ethyl ester
4-Methyl-2-oxocyclohexanecarboxylic acid ethyl ester
Cyclohexanecarboxylic acid, 4-methyl-2-oxo-, ethyl ester | [EINECS(EC#)]
236-910-1 | [Molecular Formula]
C10H16O3 | [MDL Number]
MFCD00001632 | [MOL File]
13537-82-1.mol | [Molecular Weight]
184.23 |
| Chemical Properties | Back Directory | [Melting point ]
53-54 °C | [Boiling point ]
128-132 °C/32 mmHg (lit.) | [density ]
1.045 g/mL at 25 °C (lit.) | [vapor pressure ]
28Pa at 25℃ | [refractive index ]
n20/D 1.473(lit.) | [Fp ]
>230 °F | [pka]
12.09±0.40(Predicted) | [Water Solubility ]
2.56g/L at 20℃ | [LogP]
4.36 at 30℃ |
| Hazard Information | Back Directory | [Uses]
2-Carbethoxy-5-methylcyclohexanone is a useful chemical reagent in organic synthesis. It is reported that 2-Carbethoxy-5-methylcyclohexanone is used in the synthesis of optically active α-methylene γ-butyrolactones and (+)-mintlactone. | [Uses]
Reactant involved in:• ;Hydroxylation / oxidative chlorination with hydrogen peroxide1• ;Heterocyclization2• ;Cyclization of generated dianions followed by dehydrogenation3• ;Palladium-catalyzed isomerization4• ;Regioselective cyclizations5• ;Vinylogous Michael reactions6 | [Uses]
Reactant involved in:
- Hydroxylation / oxidative chlorination with hydrogen peroxide
- Heterocyclization
- Cyclization of generated dianions followed by dehydrogenation
- Palladium-catalyzed isomerization
- Regioselective cyclizations
- Vinylogous Michael reactions
| [Flammability and Explosibility]
Notclassified |
|
| Company Name: |
Energy Chemical
|
| Tel: |
021-021-58432009 400-005-6266 |
| Website: |
http://www.energy-chemical.com |
| Company Name: |
Sigma-Aldrich
|
| Tel: |
021-61415566 800-8193336 |
| Website: |
https://www.sigmaaldrich.cn |
| Company Name: |
Merck KGaA
|
| Tel: |
21-20338288 |
| Website: |
www.sigmaaldrich.cn |
|