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1365531-89-0

1365531-89-0 Structure

1365531-89-0 Structure
IdentificationBack Directory
[Name]

(R)-2,2'-Bis[bis(3,5-diMethylphenyl)phosphino]-4,4',6,6'-tetraMethoxybiphenyl, 97+%
[CAS]

1365531-89-0
[Synonyms]

(R)-2,2'-Bis[bis(3,5-diMethylphenyl)phosphino]-4,4',6,6'-tetraMethoxybiphenyl, 97+%
(R)-2,2'-Bis[bis(3,5-dimethylphenyl)phosphino]-4,4',6,6'-tetramethoxy-)-1,1'-biphenyl
(R)-2,2'-Bis[bis(3,5-diMethylphenyl)phosphino]-4,4',6,6'-tetraMethoxybiphenyl, Min. 97% (R)-Xyl-Garphos
(R)-2,2'-Bis[bis(3,5-dimethylphenyl)phosphino]-4,4',6,6'-tetramethoxy-)-1,1'-biphenyl, min. 97% (R)-Xyl-Garphos(TM)
[Molecular Formula]

C48H52O4P2
[MDL Number]

MFCD19443624
[MOL File]

1365531-89-0.mol
[Molecular Weight]

754.872
Chemical PropertiesBack Directory
[Melting point ]

>300 °C
[Boiling point ]

810.8±65.0 °C(Predicted)
[storage temp. ]

under inert gas (nitrogen or Argon) at 2-8°C
[form ]

crystal
[color ]

white
[Optical Rotation]

[α]22/D +94.0°, c =0.5% in dichloromethane
[Sensitive ]

air sensitive
[InChIKey]

IDNKFBDRZBLTFQ-UHFFFAOYSA-N
[SMILES]

P(c3c(c(cc(c3)OC)OC)c4c(cc(cc4OC)OC)P(c6cc(cc(c6)C)C)c5cc(cc(c5)C)C)(c2cc(cc(c2)C)C)c1cc(cc(c1)C)C
Safety DataBack Directory
[Symbol(GHS) ]

Exclamation Mark (GHS07)
GHS07
[Signal word ]

Warning
[Hazard statements ]

H315-H319-H335
[Precautionary statements ]

P261-P264-P271-P280-P302+P352-P305+P351+P338
[WGK Germany ]

WGK 3
[Storage Class]

11 - Combustible Solids
[Hazard Classifications]

Eye Irrit. 2
Skin Irrit. 2
STOT SE 3
Questions And AnswerBack Directory
[Reaction]

Chiral ligand used in the preparation of hydrogenation catalysts with exceptionally high activity and selectivity. Reactions of 1365531-89-0
Hazard InformationBack Directory
[reaction suitability]

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand
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