| Identification | Back Directory | [Name]
BIS(3,5-DIMETHYL-4-METHOXYPHENYL)CHLOROPHOSPHINE | [CAS]
136802-85-2 | [Synonyms]
BIS(3,5-DIMETHYL-4-METHOXYPHENYL)CHLOROPHOSPHINE
chloro-bis(4-methoxy-3,5-dimethylphenyl)phosphane
Chlorobis(3,5-dimethyl-4-methoxyphenyl)phosphine, 98+%
Bis(3,5-diMethyl-4-Methoxyphenyl)chlorophosphine,Min.98%
Phosphinous chloride, P,P-bis(4-methoxy-3,5-dimethylphenyl)- | [Molecular Formula]
C18H22ClO2P | [MDL Number]
MFCD01630810 | [MOL File]
136802-85-2.mol | [Molecular Weight]
336.79 |
| Chemical Properties | Back Directory | [Boiling point ]
451.7±45.0 °C(Predicted) | [density ]
1.141 g/cm 3 at 25 °C | [refractive index ]
n20/D1.597 | [Fp ]
>110℃ | [form ]
liquid | [color ]
colorless, viscous | [Sensitive ]
Moisture Sensitive | [InChI]
InChI=1S/C18H22ClO2P/c1-11-7-15(8-12(2)17(11)20-5)22(19)16-9-13(3)18(21-6)14(4)10-16/h7-10H,1-6H3 | [InChIKey]
JWCZKGYRAINWJA-UHFFFAOYSA-N | [SMILES]
P(C1=CC(C)=C(OC)C(C)=C1)(C1=CC(C)=C(OC)C(C)=C1)Cl |
| Safety Data | Back Directory | [Hazard Codes ]
C | [Risk Statements ]
34 | [Safety Statements ]
26-36/37/39-43-45 | [RIDADR ]
UN3265 | [WGK Germany ]
3 | [HazardClass ]
8 | [PackingGroup ]
II | [Storage Class]
8A - Combustible corrosive hazardous materials | [Hazard Classifications]
Skin Corr. 1B |
| Hazard Information | Back Directory | [Uses]
Reactant for:
- Asymmetric organocatalytic electrophilic phosphination
- Asymmetric hydroformulation using Taddol-based chiral phosphine-phosphite ligands
- Synthesis of ferrocene-based chiral diphosphines
- Alcoholysis of phosphane-boranes
- Asymmetric hydrogenations of bifep-type biferrocenes
| [reaction suitability]
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand |
|
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