| Identification | Back Directory | [Name]
5,10,15,20-TETRAPHENYL-21H,23H-PORPHINE NICKEL(II) | [CAS]
14172-92-0 | [Synonyms]
NICKEL TPP
RARECHEM AS SA 0006
PROTOPORPHYRIN IX NI(II)
Nickel tetraphenylporphine
Nickel tetraphenylporphyrin
NI(II) MESO-TETRAPHENYLPORPHINE
NICKEL MESO-TETRAPHENYLPORPHINE
Nickel(II) tetraphenylphorphyrin
Nickel MESO-TETRAPHENYLPORPHYRIN
NICKEL(II)MESO-TETRAPHENYLPORPHINE
Tetraphenylporphine nickel complex
5,10,15,20-TETRAPHENYLPORPHYRIN NI(II)
[meso-Tetraphenylporphinato(2-)]nickel
Nickel(II) 5,10,15,20-tetraphenylporphine
[5,10,15,20-Tetraphenylporphinato(2-)]nickel
Ni(II) meso-Tetraphenylporphine (chlorin free)
5,10,15,20-Tetraphenyl-21H,23H-porphine nickel
Nickel, [5,10,15,20-tetraphenylporphinato(2-)]-
5,10,15,20-TETRAPHENYL-21H,23H-PORPHINE NICKEL(II)
21H,23H-Porphine, 5,10,15,20-tetraphenyl-, nickel complex
5,10,15,20-TETRAPHENYL-21H,23H-PORPHINE NICKEL(II), SYNTHETIC
5,10,15,20-Tetraphenyl-21H,23H-porphine nickel(II),Nickel TPP
5,10,15,20-Tetraphenyl-21H,23H-porphine nickel(II), synthetic 500MG
5,10,15,20-Tetraphenyl-21H,23H-porphine nickel(II) dye content >=95 %
Nickel, [5,10,15,20-tetraphenyl-21H,23H-porphinato(2-)-N21,N22,N23,N24]-, (SP-4-1)-
ACetic acid, 2,2',2'',2'''-[21H,23H-porphine-5,10,15,20-tetrayltetrakis(4,1-phenyleneoxy)]tetrakis-
Nickel,[5,10,15,20-tetraphenyl-21H,23H-porphinato(2-)-N21,N22,N23,N24]-(SP-4-1)- | [Molecular Formula]
C44H28N4Ni | [MDL Number]
MFCD00010727 | [MOL File]
14172-92-0.mol | [Molecular Weight]
671.41 |
| Chemical Properties | Back Directory | [Appearance]
dark purple crystalline powder or crystals | [Melting point ]
>300 °C | [storage temp. ]
2-8°C, protect from light, stored under nitrogen | [form ]
crystal | [color ]
purple | [Water Solubility ]
Insoluble in H2O; soluble in CHCl3; slightly soluble in ether, benzene, hexane, and methanol. | [λmax]
525 nm (2nd) | [InChIKey]
CXIRWLOIAQYBLZ-DAJBKUBHSA-N | [SMILES]
N12[Ni]N3C4C=CC3=C(C3C=CC(N=3)=C(C3=CC=CC=C3)C1=CC=C2C(C1=CC=CC=C1)=C1C=CC(C=4C2=CC=CC=C2)=N1)C1=CC=CC=C1 |c:7,14,41,t:36| |
| Hazard Information | Back Directory | [Chemical Properties]
dark purple crystalline powder or crystals | [Uses]
Nickel(II) Tetraphenylporphyrinate is an electron transfer agent and catalyst for aryl halogen exchange reactions. It could be used in cyclizations of saturated ο-iodo ketones and hydrogenation of alkenes.
| [reaction suitability]
reagent type: catalyst
core: nickel | [Purification Methods]
Purify it by chromatography on neutral (Grade I) alumina, followed by recrystallisation from CH2Cl2/MeOH [Yamashita J Phys Chem 91 3055 1987]. [Beilstein 26 III/IV 1960.] | [Precautions]
Stable in air and water. Some nickel compounds are known carcinogens, so standard safety precautions apply.
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| Safety Data | Back Directory | [Hazard Codes ]
Xn | [Risk Statements ]
20/21/22 | [Safety Statements ]
37/39-26-36 | [WGK Germany ]
3 | [HS Code ]
29310099 | [Storage Class]
11 - Combustible Solids | [Hazard Classifications]
Acute Tox. 4 Dermal
Acute Tox. 4 Inhalation
Acute Tox. 4 Oral |
| Spectrum Detail | Back Directory | [Spectrum Detail]
5,10,15,20-TETRAPHENYL-21H,23H-PORPHINE NICKEL(II)(14172-92-0)MS
5,10,15,20-TETRAPHENYL-21H,23H-PORPHINE NICKEL(II)(14172-92-0)IR1
5,10,15,20-TETRAPHENYL-21H,23H-PORPHINE NICKEL(II)(14172-92-0)IR2
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