| Identification | Back Directory | [Name]
BIS(3,5-DI(TRIFLUOROMETHYL)PHENYL)CHLOROPHOSPHINE | [CAS]
142421-57-6 | [Synonyms]
BIS(3,5-DI(TRIFLUOROMETHYL)PHENYL)CHLOROPHOSPHINE
BIS[BIS(3,5-TRIFLUOROMETHYL)PHENYL]CHLOROPHOSPHINE
Chlorobis[3,5-bis(trifluoromethyl)phenyl]phosphine
Bis(3,5-bis(trifluoromethyl)phenyl)chlorophosphine
Bis(3,5-Bis(Trifluoromethyl)Ohenyl)Chlorophosphane
bis[3,5-bis(trifluoromethyl)phenyl]-chlorophosphane
Chlorobis[3,5-bis(trifluoromethyl)phenyl]phosphine, 98+%
Bis(3,5-di(trifluoroMethyl)phenyl)chlorophosphine,Min.98%
P,P-Bis[3,5-bis(trifluoromethyl)phenyl]phosphinous chloride
Phosphinous chloride, P,P-bis[3,5-bis(trifluoromethyl)phenyl]-
High purity CAS 142421-57-6 BIS(3,5-DI(TRIFLUOROMETHYL)PHENYL)CHLOROPHOSPHINE in stock
Chlorobis[3,5-bis(trifluoromethyl)phenyl]phosphine, 98+%, may contain suspended dimethylamine hydrochloride crystals | [Molecular Formula]
C16H6ClF12P | [MDL Number]
MFCD01630852 | [MOL File]
142421-57-6.mol | [Molecular Weight]
492.63 |
| Chemical Properties | Back Directory | [Melting point ]
25-29 °C | [Boiling point ]
333.2±42.0 °C(Predicted) | [form ]
liquid | [color ]
colorless | [Water Solubility ]
Reacts with water. | [Sensitive ]
Moisture Sensitive | [InChI]
1S/C16H6ClF12P/c17-30(11-3-7(13(18,19)20)1-8(4-11)14(21,22)23)12-5-9(15(24,25)26)2-10(6-12)16(27,28)29/h1-6H | [InChIKey]
DFZQEHBNAJGDCT-UHFFFAOYSA-N | [SMILES]
FC(F)(F)c1cc(cc(c1)C(F)(F)F)P(Cl)c2cc(cc(c2)C(F)(F)F)C(F)(F)F |
| Safety Data | Back Directory | [Hazard Codes ]
C | [Risk Statements ]
14-34 | [Safety Statements ]
26-36/37/39-45 | [RIDADR ]
UN3265 | [WGK Germany ]
3 | [HazardClass ]
8 | [PackingGroup ]
II | [Storage Class]
4.3 - Hazardous materials which set free flammable gases upon contact with water | [Hazard Classifications]
Skin Corr. 1B
Water-react 3 |
| Hazard Information | Back Directory | [Uses]
Chlorobis[3,5-bis(trifluoromethyl)phenyl]phosphine is used as a reactant for the synthesis of chiral phosphine-aminophosphine ligands for rhodium-catalyzed asymmetric hydrogenation, ligands for palladium-catalyzed stereoselective allylation reactions, enantioselective hydrogenations, Josiphos analog as catalyst for asymmetric hydrogenation, ligands used in asymmetric hydrovinylation reactions. | [reaction suitability]
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand |
|
| Company Name: |
Alfa Aesar
|
| Tel: |
400-6106006 |
| Website: |
http://chemicals.thermofisher.cn |
| Company Name: |
Energy Chemical
|
| Tel: |
021-021-58432009 400-005-6266 |
| Website: |
http://www.energy-chemical.com |
| Company Name: |
Sigma-Aldrich
|
| Tel: |
021-61415566 800-8193336 |
| Website: |
https://www.sigmaaldrich.cn |
|