ChemicalBook--->CAS DataBase List--->1445085-92-6

1445085-92-6

1445085-92-6 Structure

1445085-92-6 Structure
IdentificationBack Directory
[Name]

Methanesulfonato2-Di-t-butylphosphino-2'-(N,N-dimethylamino)biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II)
[CAS]

1445085-92-6
[Synonyms]

t-BuDavePhos Pd G3
Methanesulfonato2-Di-t-butylphosphino-2'-(N,N-dimethylamino)biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II)
[Molecular Formula]

C35H45N2O3PPdS
[MOL File]

1445085-92-6.mol
[Molecular Weight]

711.21
Chemical PropertiesBack Directory
[form ]

Powder
[color ]

green-yellow
[CAS DataBase Reference]

1445085-92-6
Questions And AnswerBack Directory
[Reaction]

  1. Palladium precatalyst for Suzuki-Miyaura coupling reactions.
  2. Palladium precatalyst for arylation reactions of primary amines, secondary amines, primary amides, phenols, alcohols, tert-butyl acetate.
  3. Palladium precatalyst for fluorination reactions
Reactions of 1445085-92-6_1
Reactions of 1445085-92-6_2
Hazard InformationBack Directory
[Uses]

tBuDavePhos Pd G3 has been used as a precatalyst for the Synthesis of Aryl Sulfonamides via Palladium-Catalyzed Chlorosulfonylation of Arylboronic Acids. It may also be used for a variety of C-C and C-N cross-coupling reactions.
[General Description]

tBuDavePhos Pd G3 is a third generation (G3) Buchwald precatalyst. It is air, moisture and thermally-stable and is highly soluble in a wide range of common organic solvents. It has a long life in solutions. tBuDavePhos Pd G3 is an excellent reagent for palladium catalyzed cross-coupling reactions. Some of its unique features include lower catalyst loadings, shorter reaction time, efficient formation of the active catalytic species and accurate control of ligand: palladium ratio.
[reaction suitability]

core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst
reaction type: Cross Couplings
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