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145214-57-9

145214-57-9 Structure

145214-57-9 Structure
IdentificationBack Directory
[Name]

(R)-(+)-2,2'-Bis(di-2-furanylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97%
[CAS]

145214-57-9
[Synonyms]

SL-A108-1
(6,6'-Dimethoxy-2,2'-Biphenyldiyl)Bis(Di-2-Furylphosphine)
(R)-(6,6μ-Dimethoxybiphenyl-2,2μ-diyl)bis(di-2-furylphosphine)
(R)-(+)-2,2'-Bis(di-2-furanylphosphino)-6,6'-dimethoxy-1,1'-biphenyl
(R)-(+)-2,2'-Bis(di-2-furanylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97%
(R)-(+)-2,2''-BIS(DI-2-FURANYLPHOSPHINO)-6,6''-DIMETHOXY-1,1''-BIPHENYL, MIN. 97%
(R)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis(di-2-furylphosphine) >=97%, optical purity ee: >=99%
(R)-2-Furyl-MeOBIPHEP, SL-A108-1, (R)-(+)-2,2μ-Bis(di-2-furylphosphino)-6,6μ-dimethoxy-1,1μ-biphenyl
[Molecular Formula]

C30H24O6P2
[MDL Number]

MFCD09753004
[MOL File]

145214-57-9.mol
[Molecular Weight]

542.462
Chemical PropertiesBack Directory
[Boiling point ]

587.5±50.0 °C(Predicted)
[form ]

Powder
[color ]

off-white
[Stability:]

store cold
[CAS DataBase Reference]

145214-57-9
Hazard InformationBack Directory
[Chemical Properties]

White powder
[Uses]

Atropisomeric MeOBIPHEP ligands
[General Description]

sold in collaboration with Solvias AG
Safety DataBack Directory
[Symbol(GHS) ]


GHS07
[Signal word ]

Warning
[Hazard statements ]

H302-H315-H319-H335
[Precautionary statements ]

P261-P280-P301+P312-P302+P352-P305+P351+P338
[WGK Germany ]

3
[HS Code ]

29321900
Questions And AnswerBack Directory
[Reactions]

1. Ligand for the copper-catalyzed diastereo- and enantioselective reactions of bis(pinacolato)diboron, 1,3-enynes and aldehydes.
2. Ligand for ruthenium-catalyzed enantioselective hydroaminomethylation of dienes and isoprene with 1,3,5- tris(aryl)-hexahydro-1,3,5-triazines.
3. Ligand for iridium-catalyzed asymmetric hydrogenation of quinoxaline-2-carboxylates.
Reactions of 145214-57-9
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